Nickel-catalyzed cross-coupling reaction of alkyl halides with organozinc and Grignard reagents with 1,3,8,10-tetraenes as additives

被引：113
|
作者：
Terao, J
Todo, H
Watanabe, H
Ikumi, A
Kambe, N
机构：
[1] Osaka Univ, Dept Mol Chem & Sci, Grad Sch Engn, Suita, Osaka 5650871, Japan
[2] Osaka Univ, Technol Ctr Atoms Mol & Ions Control, Grad Sch Engn, Suita, Osaka 5650871, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 45期
关键词：
alkyl halides; cross-coupling; Grignard reagents; nickel; organozinc reagents;
D O I：
10.1002/anie.200460246
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Essential additives: The addition of bis(1,3-butadienyl) compounds (tetraenes) was essential in the efficient Nicatalyzed cross-coupling of organozinc reagents with alkyl bromides and a tosylate (see scheme, X = C(CO2Me)2 or NCH2Ph). The efficiency of the Ni-catalyzed cross-coupling of an alkyl fluoride with a Grignard reagent was also improved by using these tetraenes.
引用
收藏
页码：6180 / 6182
页数：3
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