catena-Poly[[diaqua(1,10-phenanthroline-N,N′)cadmium(II)]-μ-(sulfato-O:O′)] and catena-poly[[diaqua(2,9-dimethyl-1,10-phenanthroline-N,N′)-cadmium(II)]-μ-(sulfato-O:O′)]

被引：17

作者：

Harvey, M

Baggio, S

Suescun, L

Baggio, RF ^{[1
]}

机构：

[1] Comis Nacl Energia Atom, Dept Fis, RA-1429 Buenos Aires, DF, Argentina

[2] Univ Nacl Patagonia, Sede Trelew & CenPat, CONICET, RA-9120 Puerto Madryn, Chubut, Argentina

[3] Univ Nacl Patagonia, Sede Puerto Madryn & GenPat, CONICET, RA-9120 Puerto Madryn, Chubut, Argentina

[4] Univ Republica, Fac Quim, CSSC Lab, Montevideo, Uruguay

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2000年 / 56卷 / 56期

关键词：

Cadmium compounds - Chemical bonds - Complexation - Crystal structure - Crystal symmetry - Molecular structure;

D O I：

10.1107/S010827010000617X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Both title compounds, [Cd(SO4)(C12H8N2)(H2O)(2)](n) and [Cd(SO4)(C14H12N2)(H2O)(2)](n), respectively, are polymeric and present the Cd atoms in very similar octahedral environments, provided by the bidentate organic ligand (phenanthroline/dimethylphenanthroline), two aqua molecules and two O atoms from two translationally related sulfate groups, which thus act as links in the resulting polymeric chains.

引用

页码：811 / 813

页数：3

共 11 条

[1]

Allen F.H., 1993, CHEM AUTOMAT NEWS, V8, P31

[2] CRYSTAL-STRUCTURE OF CIS-CATENA-MU-SULPHATO-AQUOTRIS(IMIDAZOLE)CADMIUM(II) [J].