A new indazole-based colorimetric chemosensor for sequential detection of Cu2+ and GSH in aqueous solution

被引:28
|
作者
Kim, Min Seon [1 ,2 ]
Jung, Jae Min [1 ,2 ]
Kang, Ji Hye [1 ,2 ]
Ahn, Hye Mi [1 ,2 ]
Kim, Pan-Gi [3 ]
Kim, Cheal [1 ,2 ]
机构
[1] Seoul Natl Univ Sci & Technol, Dept Fine Chem, Seoul 139743, South Korea
[2] Seoul Natl Univ Sci & Technol, Dept Interdisciplinary Bio IT Mat, Seoul 139743, South Korea
[3] Kyungpook Natl Univ, Sch Ecol & Environm Syst, Sangju 37224, South Korea
基金
新加坡国家研究基金会;
关键词
Colorimetric; Copper; Glutathione; Sequential detection; Theoretical calculations; EFFECTIVE CORE POTENTIALS; FLUORESCENT SENSOR; SELECTIVE DETECTION; METAL-IONS; MOLECULAR CALCULATIONS; BIOLOGICAL THIOLS; RELAY RECOGNITION; COPPER COMPLEX; CU(II); CYSTEINE;
D O I
10.1016/j.tet.2017.06.051
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new selective and sensitive colorimetric chemosensor 1 was developed for the sequential detection of Cu2+ and glutathione (GSH) in aqueous solution. The sensor 1 detected Cu2+ ion by an obvious color change from colorless to pale yellow. Importantly, 1 could be used to detect and quantify Cu2+ ion in water samples, and the detection limit (0.14 mu M) of 1 for Cu2+ was much lower than the guideline (31.5 mu M) of WHO in drinking water. Also, Cu2+-2.1 complex can be used as a colorimetric sensor for GSH via naked -eye. The detection limit for GSH was founded to be 2.98 mu M. Moreover, the sensing ability of 1 for Cu2+ was supported by theoretical calculations. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4750 / 4757
页数:8
相关论文
共 50 条
  • [1] A novel displacement-type colorimetric chemosensor for the detection of Cu2+ and GSH in aqueous solution
    You, Ga Rim
    Jang, Hyo Jung
    Jo, Tae Geun
    Kim, Cheal
    RSC ADVANCES, 2016, 6 (78): : 74400 - 74408
  • [2] Sequential detection of Cu2+ and cysteine using an imidazole-based chemosensor in aqueous solution
    Saha, Baptu
    Saha, Pinki
    Mandal, Abhijit
    Naskar, Jnan Prakash
    Maiti, Debasish
    Chowdhury, Shubhamoy
    JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2019, 66 (05) : 506 - 514
  • [3] A simple colorimetric chemosensor for relay detection of Cu2+ and S2- in aqueous solution
    Kim, Min Seon
    Jung, Jae Min
    Ahn, Hye Mi
    Kim, Cheal
    JOURNAL OF COORDINATION CHEMISTRY, 2018, 71 (02) : 355 - 370
  • [4] A novel colorimetric chemosensor for the sequential detection of Ni2+ and CN- in aqueous solution
    Kang, Ji Hye
    Lee, Seong Youl
    Ahn, Hye Mi
    Kim, Cheal
    SENSORS AND ACTUATORS B-CHEMICAL, 2017, 242 : 25 - 34
  • [5] A Colorimetric and Fluorescent Chemosensor for Cu2+ Detection in Aqueous Solution
    Li, Lian-Qing
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2016, 46 (12) : 1854 - 1856
  • [6] A benzothiadiazole-based colorimetric chemosensor for detecting Cu2+ and sequential H2S in practical samples
    Choe, Donghwan
    Kim, Cheal
    INORGANICA CHIMICA ACTA, 2022, 543
  • [7] A thiol-containing colorimetric chemosensor for relay recognition of Cu2+ and S2- in aqueous media with a low detection limit
    So, Haeri
    Chae, Ju Byeong
    Kim, Cheal
    INORGANICA CHIMICA ACTA, 2019, 492 : 83 - 90
  • [8] Experimental and theoretical studies of a colorimetric cu2+ chemosensor in aqueous solution
    Jo H.Y.
    Choi Y.W.
    You G.R.
    Lee J.J.
    Kim C.
    Kim, Cheal (chealkim@seoultech.ac.kr), 1600, American Scientific Publishers (14): : 178 - 185
  • [9] A new Schiff-base chemosensor for selective detection of Cu2+ and Co2+ and its copper complex for colorimetric sensing of S2- in aqueous solution
    Kim, Min Seon
    Lee, Seong Youl
    Jung, Jae Min
    Kim, Cheal
    PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2017, 16 (11) : 1677 - 1689
  • [10] A Novel Chemosensor Based on Rhodamine Derivative for Colorimetric and Fluorometric Detection of Cu2+ in Aqueous Solution
    Wang, Yu
    Wu, Hai-qiang
    Sun, Jian-hua
    Liu, Xiao-ya
    Luo, Jing
    Chen, Ming-qing
    JOURNAL OF FLUORESCENCE, 2012, 22 (03) : 799 - 805