Toward a better understanding of multifunctional cement-based materials: The impact of graphite nanoplatelets (GNPs)

被引:34
|
作者
Lamastra, Francesca R. [1 ]
Chougan, Mehdi [1 ,2 ]
Marotta, Emanuele [1 ]
Ciattini, Samuele [3 ]
Ghaffar, Seyed Hamidreza [2 ]
Caporali, Stefano [4 ]
Vivio, Francesco [1 ]
Montesperelli, Giampiero [1 ]
Ianniruberto, Ugo [5 ]
Al-Kheetan, Mazen J. [6 ]
Bianco, Alessandra [1 ]
机构
[1] Univ Roma Tor Vergata, Consortium INSTM RU Roma Tor Vergata, Dipartimento Ingn Impresa Mario Lucertini, Via Politecn, I-00133 Rome, Italy
[2] Brunel Univ London, Dept Civil & Environm Engn, Uxbridge UB8 3PH, Middx, England
[3] Univ Firenze, Ctr Cristallog Strutturale CRIST, Via Lastruccia 3, I-50019 Sesto Fiorentino, Italy
[4] Univ Firenze, Consortium INSTM RU Firenze, Dipartimento Ingn Ind DIEF, Via Santa Marta 3, I-50139 Florence, Italy
[5] Univ Roma Tor Vergata, Dipartimento Ingn Civile Informat DICII, Viale Politecn, I-00133 Rome, Italy
[6] Mutah Univ, Civil & Environm Engn Dept, POB 7, Mutah 61710, Karak, Jordan
关键词
Cementitious nanocomposites; Graphite nanoplatelets (GNPs); Mechanical properties; Microstructure; Resistivity; Thermal conductivity; GRAPHENE NANOPLATELETS; MECHANICAL-PROPERTIES; ELECTRICAL-PROPERTIES; THERMAL-CONDUCTIVITY; COMPOSITES; MICROSTRUCTURE; CONCRETE; MORTAR; ENHANCEMENT; RESISTIVITY;
D O I
10.1016/j.ceramint.2021.04.012
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The impact of graphite nanoplatelets (GNPs) on the physical and mechanical properties of cementitious nanocomposites was investigated. A market-available premixed mortar was modified with 0.01% by weight of cement of commercial GNPs characterized by two distinctively different aspect ratios. The rheological behavior of the GNP-modified fresh admixtures was thoroughly evaluated. Hardened cementitious nanocomposites were investigated in terms of density, microstructure (Scanning Electron Microscopy, SEM and micro-Computed Tomography, it-CT), mechanical properties (three-point bending and compression tests), and physical properties (electrochemical impedance spectroscopy, EIS and thermal conductivity measurements). At 28 days, all GNP-modified mortars showed about 12% increased density. Mortars reinforced with high aspect ratio GNPs exhibited the highest compressive and flexural strength: about 14% and 4% improvements compared to control sample, respectively. Conversely, low aspect ratio GNPs led to cementitious nanocomposites characterized by 36% decreased electrical resistivity combined with 60% increased thermal conductivity with respect to the control sample.
引用
收藏
页码:20019 / 20031
页数:13
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