Preparation of facile separable homogeneous Rhodium catalyst and its application for the catalytic hydrogenation of nitrile butadiene rubber and styrene-butadiene rubber

被引：16

作者：

Zhou, Wei ^{[1
]}

Yi, Jiemin ^{[1
]}

Lin, Jiawei ^{[1
]}

Fang, Shifeng ^{[1
]}

Peng, Xiaohong ^{[1
]}

机构：

[1] South China Univ Technol, Dept Mat Sci & Engn, Guangzhou 510640, Guangdong, Peoples R China

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2017年 / 43卷 / 07期

基金：

中国国家自然科学基金;

关键词：

Poly(propylene imine) dendrimer; Triolefinic macrocycle; Catalytic hydrogenation; Nitrile-butadiene rubber; Styrene-butadiene rubber; SELECTIVE HYDROGENATION; NANOPARTICLES; NBR;

D O I：

10.1007/s11164-016-2838-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Poly(propylene imine) dendrimer (G2-PPI) terminated by nitrogen-containing triolefinic macrocycle on the periphery (G2-M) was synthesized by a nucleophilic substitution reaction. The structure and composition of G2-M were characterized by FT-IR, H-1-NMR and elemental analysis. The Rh3+ dendrimer-stabilized catalyst (G2-M(Rh3+)) was prepared by utilizing G2-M as stabilizer and analyzed by UV-Vis spectroscopy, H-1-NMR spectrometry, XPS and XRD. G2-M(Rh3+) demonstrates excellent catalytic activity and selectivity for the hydrogenation of nitrile-butadiene rubber (NBR) and styrene-butadiene rubber (SBR), and Rh residue contents for HNBR and HSBR are only 35 and 13 ppm, respectively, without any post treatment.

引用

页码：3651 / 3662

页数：12

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[21] Selectively catalytic hydrogenation of styrene-butadiene rubber over Pd/g-C3N4 catalyst [J].

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