Solvothermal Synthesis and Structure of the [Co(5-NH2-bdc)(4,4′-dpdo)(H2O)]n Complex (4,4′-dpdo=4,4′-Bipyridrl-N,N′-dioxide, 5-NH2-bdc=5-Aminoisophthalic Acid)

被引:0
作者
Zhang Shu-Hua [1 ]
Jin Zhen-Jiang [1 ]
Zou Hua-Hong [2 ]
Zhong Fan [3 ]
Ge Cheng-Min [1 ]
机构
[1] Guilin Univ Technol, Guilin 541004, Peoples R China
[2] Guangxi Normal Univ, Coll Chem & Chem Engn, Guilin 541004, Peoples R China
[3] Jinggangshan Normal Coll, Dept Chem, Jian 343009, Jiangxi, Peoples R China
关键词
cobalt; crystal structure; 4,4 '-dpdo; 5-aminoisophthalic acid; FRAMEWORKS; NETWORKS; DESIGN; DRIVEN;
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The title compound [Co(5-NH2-bdc)(4,4'-dpdo)(H2O)](n) 1 (5-NH2-bdc = 5-aminoisopthalic acid, 4,4'-dpdo = 4,4'-bipyridrl-NN'-dioxide) crystallizes in triclinic, space group P (1) over bar with a = 4.999(1), b = 10.072(2), c = 13.028(3) angstrom, alpha = 107.72(3), beta = 92.58(3), gamma = 98.11(3)degrees, V = 615.9(3) angstrom(3), F(000) = 356, R-int = 0.0186, Z = 2, R = 0.0333, wR = 0.0721, S = 1.032 and (Delta/sigma)(max) = 0.001. In the molecule of 1, the Co(II) cation is coordinated by three O-atoms of two 5-NH2-bdc ligands, one N-atom of another 5-NH2-bdc ligand, one O-atom of 4,4'-dpdo and one terminal O-atom. of water molecule. The molecules construct a 2-D network through bridging 5-NH2-bdc and 4,4'-dpdo ligands, and further form a 3-D network through N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds. The network topology of 1 can be simplified as a rare 2D (3,6)-connected (4(2)6(3)8(1)) net.
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收藏
页码:1630 / 1634
页数:5
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