Catalytic multistep reactions via palladacycles

被引：216
作者：
Catellani, M [1 ]
机构：
[1] Univ Parma, Dipartimento Chim Organ & Ind, I-43100 Parma, Italy
来源：
SYNLETT | 2003年 / 03期
关键词：
multistep reactions; palladium(IV); palladacycle; deinsertion; C-H activation;
D O I：
10.1055/s-2003-37102
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This account reports new methodologies to achieve multistep reactions under the catalytic action of palladium complexes. The metal control enables molecular pools consisting of several components to react in a definite order to form products with high chemo-, regio- and stereoselectivity. Key intermediates are palladacycles, which are formed and dismantled in the course of the reaction sequence.
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收藏
页码：298 / 313
页数：16
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