Nitrogen-containing mesoporous carbon cathode for lithium-oxygen batteries: The influence of Nitrogen on oxygen reduction reaction

被引：19

作者：

Nie, Hongjiao ^{[1
,2
]}

Zhang, Yining ^{[1
]}

Zhou, Wei ^{[1
,2
]}

Li, Jing ^{[1
,2
]}

Wu, Baoshan ^{[1
]}

Liu, Tao ^{[1
]}

Zhang, Huamin ^{[1
]}

机构：

[1] Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Dalian 116023, Peoples R China

[2] Univ Chinese Acad Sci, Beijing 100039, Peoples R China

来源：

ELECTROCHIMICA ACTA | 2014年 / 150卷

关键词：

Lithium-oxygen battery; carbon cathode; nitrogen doping; oxygen reduction reaction activity; quaternary nitrogen; DOPED GRAPHENE NANOSHEETS; ELECTROLYTE FUEL-CELLS; ORGANIC ELECTROLYTE; ENERGY-STORAGE; ACTIVE-SITES; CATALYSTS; GRAPHITE; EDGE; MIXTURES; STATE;

D O I：

10.1016/j.electacta.2014.10.138

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The direct effect of nitrogen content and various nitrogen species on oxygen reduction reaction (ORR) activities in non-aqueous lithium-oxygen (Li-O-2) batteries are systematically investigated. Mesoporous carbon (MC) with various nitrogen species is prepared through heat treatment of N-containing precursor under different temperature. The effect of the heat treatment temperature on the performance of carbon materials in Li-O-2 battery is investigated. The bonding state of nitrogen atoms is found to have a significant effect on the ORR activity. The ORR activity in Li-O-2 battery is proved to be dependent on the quaternary N content while the total N content in the carbon material does not play a crucial role in the ORR process. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：205 / 210

页数：6

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