ESI and tandem MS for mechanistic studies with high-valent transition metal species

被引：2
作者：
Bleher, Katharina [1 ]
Comba, Peter [1 ,2 ]
Gross, Juergen H. [3 ]
Josephy, Thomas [1 ]
机构：
[1] Heidelberg Univ, Anorgan Chem Inst, INF 270, D-69120 Heidelberg, Germany
[2] Interdisziplinares Zentrum Wissensch Rechnen IWR, Heidelberg, Germany
[3] Heidelberg Univ, Organ Chem Inst, INF 270, D-69120 Heidelberg, Germany
来源：
DALTON TRANSACTIONS | 2022年 / 51卷 / 22期
关键词：
ELECTROSPRAY MASS-SPECTROMETRY; ION-CYCLOTRON RESONANCE; COLLISION-INDUCED DECOMPOSITION; GAS-PHASE REACTIONS; C-H; SPECTROSCOPIC CHARACTERIZATION; IRON(IV)-OXO COMPLEX; SPIN-STATE; BOND ACTIVATION; POSITIVE-ION;
D O I：
10.1039/d2dt00809b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The analysis of high-valent metal species has been in the focus of research for over 20 years. Mass spectrometry (MS) represents a technique routinely used for their characterization, in particular electrospray ionization mass spectrometry (ESI-MS) and cold-spray ionization-mass spectrometry (CSI-MS). The combination of both methods with tandem MS provides additional tools for understanding decay processes and reaction pathways. In this Perspective, tandem ESI-MS, an important instrument in enzyme and peptide characterization and organometallic chemistry, is discussed as a valuable tool for the elucidation of reaction mechanisms of high-valent metal species.
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收藏
页码：8625 / 8639
页数：15
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