The first sideways-bonded peroxo complex for a tetraaminecobalt(III) species
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Rahman, AFMM
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机构:Univ New S Wales, Univ Coll, Sch Phys Environm & Math Sci, Canberra, ACT 2600, Australia
Rahman, AFMM
Jackson, WG
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Univ New S Wales, Univ Coll, Sch Phys Environm & Math Sci, Canberra, ACT 2600, AustraliaUniv New S Wales, Univ Coll, Sch Phys Environm & Math Sci, Canberra, ACT 2600, Australia
Jackson, WG
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Willis, AC
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机构:Univ New S Wales, Univ Coll, Sch Phys Environm & Math Sci, Canberra, ACT 2600, Australia
Willis, AC
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[1] Univ New S Wales, Univ Coll, Sch Phys Environm & Math Sci, Canberra, ACT 2600, Australia
[2] Australian Natl Univ, Res Sch Chem, Canberra, ACT 0200, Australia
Cobalt(II) salts react with H2O2 in the presence of 2 equiv of tetramethylethylenediamine (tmen) to produce a stable sideways bonded mononuclear peroxo complex [Co(tmen)(2)O-2]ClO4 which has been characterized chemically and by a single crystal X-ray determination. This is the first such tetraaminecobalt(III) complex, indeed, the first for any tetraaminemetal ion complex. The mononuclear peroxo complex can also be synthesized by O-2(2-)-anation of cis-[Co(tmen)(2)(OH2)(2)](3+). This reaction is reversed in acid, and this offers the potential to develop Co(III) catalyzed oxidation reactions.
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Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, JapanTokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
Hikichi, S
Akita, M
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Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, JapanTokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
Akita, M
Moro-Oka, Y
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Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, JapanTokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
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Univ New S Wales, Australian Def Force Acad, Univ Coll, Sch Chem, Canberra, ACT 2600, AustraliaUniv New S Wales, Australian Def Force Acad, Univ Coll, Sch Chem, Canberra, ACT 2600, Australia
Jackson, WG
Rahman, AFMM
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Univ New S Wales, Australian Def Force Acad, Univ Coll, Sch Chem, Canberra, ACT 2600, AustraliaUniv New S Wales, Australian Def Force Acad, Univ Coll, Sch Chem, Canberra, ACT 2600, Australia
Rahman, AFMM
Wong, MA
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Univ New S Wales, Australian Def Force Acad, Univ Coll, Sch Chem, Canberra, ACT 2600, AustraliaUniv New S Wales, Australian Def Force Acad, Univ Coll, Sch Chem, Canberra, ACT 2600, Australia
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Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, JapanTokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
Hikichi, S
Akita, M
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Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, JapanTokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
Akita, M
Moro-Oka, Y
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Tokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, JapanTokyo Inst Technol, Resources Utilizat Res Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
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Univ New S Wales, Australian Def Force Acad, Univ Coll, Sch Chem, Canberra, ACT 2600, AustraliaUniv New S Wales, Australian Def Force Acad, Univ Coll, Sch Chem, Canberra, ACT 2600, Australia
Jackson, WG
Rahman, AFMM
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Univ New S Wales, Australian Def Force Acad, Univ Coll, Sch Chem, Canberra, ACT 2600, AustraliaUniv New S Wales, Australian Def Force Acad, Univ Coll, Sch Chem, Canberra, ACT 2600, Australia
Rahman, AFMM
Wong, MA
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Univ New S Wales, Australian Def Force Acad, Univ Coll, Sch Chem, Canberra, ACT 2600, AustraliaUniv New S Wales, Australian Def Force Acad, Univ Coll, Sch Chem, Canberra, ACT 2600, Australia