Identifying Fundamental Limitations in Halide Perovskite Solar Cells

被引：134

作者：

Leong, Wei Lin ^{[1
]}

Ooi, Zi-En ^{[1
]}

Sabba, Dharani ^{[2
]}

Yi, Chenyi ^{[3
]}

Zakeeruddin, Shaik M. ^{[3
]}

Graetzel, Michael ^{[3
]}

Gordon, Jeffrey M. ^{[4
]}

Katz, Eugene A. ^{[4
]}

Mathews, Nripan ^{[2
,5
]}

机构：

[1] ASTAR, Inst Mat Res & Engn, 2 Fusionopolis Way,Innovis 08-03, Singapore 138634, Singapore

[2] Energy Res Inst NTU ERI N, Res Techno Plaza,X Frontier Block,Level 5, Singapore 637553, Singapore

[3] Ecole Polytech Fed Lausanne, Lab Photon & Interfaces, CH-1015 Lausanne, Switzerland

[4] Ben Gurion Univ Negev, Jacob Blaustein Inst Desert Res, Dept Solar Energy & Environm Phys, Sede Boqer Campus, IL-84990 Sede Boqer, Israel

[5] Nanyang Technol Univ, Sch Mat Sci & Engn, 50 Nanyang Ave, Singapore 639798, Singapore

来源：

ADVANCED MATERIALS | 2016年 / 28卷 / 12期

关键词：

TEMPERATURE-DEPENDENCE; RECOMBINATION; EFFICIENCY; BEHAVIOR; LIGHT;

D O I：

10.1002/adma.201505480

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The temperature dependence of the principal photovoltaic parameters of perovskite photovoltaics is studied. The recombination activation energy is in good agreement with the perovskite's bandgap energy, thereby placing an upper bound on the open-circuit voltage. The photocurrent increases moderately with temperature and remains high at low temperature, reinforcing that the cells are not hindered by insufficient thermally activated mobility or carrier trapping by deep defects. [GRAPHICS] .

引用

页码：2439 / 2445

页数：7

共 46 条

[1] Temperature dependence of hole conductor free formamidinium lead iodide perovskite based solar cells [J].

Aharon, Sigalit ;

Dymshits, Alexander ;

Rotem, Amit ;

Etgar, Lioz .

JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (17) :9171-9178

[2]

[Anonymous], Best Research Cell Efficiencies

[3] Temperature dependence of polymer/fullerene organic solar cells [J].

Bagienski, W. ;

Gupta, M. C. .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2011, 95 (03) :933-941

[4] Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3) PbI3 for solid-state sensitised solar cell applications [J].

Baikie, Tom ;

Fang, Yanan ;

Kadro, Jeannette M. ;

Schreyer, Martin ;

Wei, Fengxia ;

Mhaisalkar, Subodh G. ;

Graetzel, Michael ;

White, Tim J. .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (18) :5628-5641

[5] Thiols Passivate Recombination Centers in Colloidal Quantum Dots Leading to Enhanced Photovoltaic Device Efficiency [J].

Barkhouse, D. Aaron R. ;

Pattantyus-Abraham, Andras G. ;

Levina, Larissa ;

Sargent, Edward H. .

ACS NANO, 2008, 2 (11) :2356-2362

[6] Real-space observation of unbalanced charge distribution inside a perovskite-sensitized solar cell [J].

Bergmann, Victor W. ;

Weber, Stefan A. L. ;

Javier Ramos, F. ;

Nazeeruddin, Mohammad Khaja ;

Graetzel, Michael ;

Li, Dan ;

Domanski, Anna L. ;

Lieberwirth, Ingo ;

Ahmad, Shahzada ;

Berger, Ruediger .

NATURE COMMUNICATIONS, 2014, 5

[7] Relationship between energetic disorder and open-circuit voltage in bulk heterojunction organic solar cells [J].

Blakesley, James C. ;

Neher, Dieter .

PHYSICAL REVIEW B, 2011, 84 (07)

[8] The expanding world of hybrid perovskites: materials properties and emerging applications [J].

Brittman, Sarah ;

Adhyaksa, Gede Widia Pratama ;

Garnett, Erik Christian .

MRS COMMUNICATIONS, 2015, 5 (01) :7-26

[9] Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].

Burschka, Julian ;

Pellet, Norman ;

Moon, Soo-Jin ;

Humphry-Baker, Robin ;

Gao, Peng ;

Nazeeruddin, Mohammad K. ;

Graetzel, Michael .

NATURE, 2013, 499 (7458) :316-+

[10] Lead iodide perovskite light-emitting field-effect transistor [J].

Chin, Xin Yu ;

Cortecchia, Daniele ;

Yin, Jun ;

Bruno, Annalisa ;

Soci, Cesare .

NATURE COMMUNICATIONS, 2015, 6

← 1 2 3 4 5 →