Selective Oxidation of Sulfides to Sulfones Using H2O2 and Anderson-Type Hexamolybdochromate(III) as Catalyst

被引：10

作者：

Supale, Amit R. ^{[1
]}

Gokavi, Gavisiddappa S. ^{[1
]}

机构：

[1] Shivaji Univ, Dept Chem, Kinet & Catalysis Lab, Kolhapur 416004, Maharashtra, India

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2010年 / 185卷 / 04期

关键词：

Hexamolybdochromate (III); homogeneous catalysis; hydrogen peroxide; oxidation; sulfones; SULFOXIDES; EFFICIENT; THIOLS; ACID;

D O I：

10.1080/10426500902922958

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An Anderson-type hexamolybdochromate(III) is found to be an effective catalyst for the selective oxidation of sulfides to their corresponding sulfones. The reaction was carried out in 60% aq. acetonitrile (v/v) using 30% H2O2 at 60 degrees C. Various dialkyl, alkyl-aryl, and diaryl sulfides were selectively oxidized, giving high yields of sulfones after a simple workup procedure.

引用

页码：725 / 731

页数：7

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