Selective Oxidation of Sulfides to Sulfones Using H2O2 and Anderson-Type Hexamolybdochromate(III) as Catalyst

被引：10
作者：
Supale, Amit R. [1 ]
Gokavi, Gavisiddappa S. [1 ]
机构：
[1] Shivaji Univ, Dept Chem, Kinet & Catalysis Lab, Kolhapur 416004, Maharashtra, India
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2010年 / 185卷 / 04期
关键词：
Hexamolybdochromate (III); homogeneous catalysis; hydrogen peroxide; oxidation; sulfones; SULFOXIDES; EFFICIENT; THIOLS; ACID;
D O I：
10.1080/10426500902922958
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An Anderson-type hexamolybdochromate(III) is found to be an effective catalyst for the selective oxidation of sulfides to their corresponding sulfones. The reaction was carried out in 60% aq. acetonitrile (v/v) using 30% H2O2 at 60 degrees C. Various dialkyl, alkyl-aryl, and diaryl sulfides were selectively oxidized, giving high yields of sulfones after a simple workup procedure.
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收藏
页码：725 / 731
页数：7
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