Atomic-layer surface reaction of SiH4 on Ge(100)

被引:23
|
作者
Watanabe, T [1 ]
Sakuraba, M [1 ]
Matsuura, T [1 ]
Murota, J [1 ]
机构
[1] Tohoku Univ, Elect Commun Res Inst, Lab Elect Intelligent Syst, Aoba Ku, Sendai, Miyagi 98077, Japan
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS | 1997年 / 36卷 / 6B期
关键词
single atomic layer; dimer structure; hydride;
D O I
10.1143/JJAP.36.4042
中图分类号
O59 [应用物理学];
学科分类号
摘要
The single atomic layer growth process of Si on a Ge(100) surface using SiH4 has been investigated by ultraclean cold-wall low-pressure chemical vapor deposition (CVD). Self-limiting reaction of SiH4 on the Ge surface was found at 260 degrees C and the reaction step can be explained by Langmuir-type kinetics. The saturated surface concentration of Si atoms depends on the preheating conditions. A single atomic layer was found for preheating at 350 degrees C in Ar and at 260 degrees C in H-2. However, in the case of preheating in H-2 at 350 degrees C, the Si atom concentration hardly reached that of a single atomic layer. Reflection high-energy electron diffraction (RHEED) and Fourier-transform infrared reflection adsorption spectroscopy (FTIR/RAS) observations showed that a H-terminated dimer structure was formed on the Ge(100) surface after preheating in H-2 at 350 degrees C. The density of the SiH4 reaction sites on the H-terminated surface with the dimer structure is considered to be lower than that of the H-terminated unreconstructed surface and the H-free surface.
引用
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页码:4042 / 4045
页数:4
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