catena-Poly[[(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)cadmium(II)]-di-μ-iodido]

被引：13

作者：

Ahmadi, Roya ^{[1
]}

Kalateh, Khadijeh ^{[1
]}

Amani, Vahid ^{[1
]}

机构：

[1] Islamic Azad Univ, Shahr e Rey Branch, Tehran, Iran

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

COMPLEXES; LIGANDS;

D O I：

10.1107/S1600536810014091

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title coordination polymer, [CdI2(C12H12N2)](n), the Cd2+ ion lies on a twofold rotation axis: it is six-coordinated in a distorted cis-CdN2I4 octahedral geometry by two N atoms from a chelating 5,5'-dimethyl-2,2'-bipyridine ligands and four bridging iodide anions. The bridging function of the iodide ions leads to a chain structure propagating in [001].

引用

页码：M562 / U858

页数：8

共 15 条

[1] catena-poly[[(5,5′-dimethyl-2,2′-bipyridine-κ2N,N′)cadmium(II)]-di-μ-chlorido] [J].

Ahmadi, Roya ;

Khalighi, Aida ;

Kalateh, Khadijeh ;

Amani, Vahid ;

Khavasi, Hamid Reza .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M1233-U184

[2]

Albada G. A., 2004, EUR J INORG CHEM, P3733

[3] Synthesis, characterization and crystal structure determination of iron(III) hetero-ligand complexes containing 2,2′-bipyridine, 5,5′-dimethyl-2,2′-bipyridine and chloride, [Fe(bipy)Cl4][bipy•H] and [Fe(dmbipy)2Cl2][FeCl4] [J].

Amani, Vahid ;

Safari, Nasser ;

Khavasi, Hamid Reza .

POLYHEDRON, 2007, 26 (15) :4257-4262

[4] Synthesis, characterization and crystal structure determination of platinum(IV) complexes containing, bipyridine derivatives and chloride, [Pt(5,5′-dmbipy)Cl4] and [Pt(6-mbipy)Cl4] [J].

Amani, Vahid ;

Safari, Nasser ;

Khavasi, Hamid Reza ;

Akkurt, Mehmet .

POLYHEDRON, 2009, 28 (14) :3026-3030

[5]

[Anonymous], 1998, SMART SAINT SADABS

[6] Cadmium-halide and mixed cadmium-halide-dicyanamide polymers mediated by ancillary 2-aminoalkyl-pyridine ligands: Synthesis, X-ray single crystal structures and luminescence property [J].

Chattopadhyay, Tanmay ;

Banerjee, Arpita ;

Banu, Kazi Sabnam ;

Suresh, Eringathodi ;

Netahji, Munirathinam ;

Birarda, Giovanni ;

Zangrando, Ennio ;

Das, Debasis .

POLYHEDRON, 2008, 27 (11) :2452-2458

[7]

Farrugia L. J., 1999, Journal of Applied Crystallography, V32, P837, DOI [DOI 10.1107/S0021889812029111, 10.1107/S0021889899006020, DOI 10.1107/S0021889899006020]

[8] catena-poly[[(1,10-phenanthroline-κ2N,N′)-cadmium(II)]-di-μ-iodo] [J].