Cooperation of a Nickel-Bipyridine Complex with Light for Benzylic C-H Arylation of Toluene Derivatives

被引：33

作者：

Ishida, Naoki ^{[1
]}

Masuda, Yusuke ^{[1
]}

Ishikawa, Norikazu ^{[1
]}

Murakami, Masahiro ^{[1
]}

机构：

[1] Kyoto Univ, Dept Synthet Chem & Biol Chem, Kyoto 6158510, Japan

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 6卷 / 06期

关键词：

C-C coupling; C-H activation; homogeneous catalysis; nickel; photocatalysis; PHOTOREDOX CATALYSIS; VISIBLE-LIGHT; BOND ACTIVATION; FUNCTIONALIZATION; MECHANISM; HALIDES;

D O I：

10.1002/ajoc.201700115

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Benzylic C-H bonds of toluene derivatives are directly arylated with aryl bromides by means of a catalytic system of nickel-bipyridine under irradiation with UV light. The catalyst system is simple and all the components are readily available, and thus, the present system offers a convenient maneuver to shape aryl-benzyl linkages.

引用

页码：669 / 672

页数：4

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