Effective and selective iodofunctionalisation of organic molecules in water using the iodine-hydrogen peroxide tandem

被引：86

作者：

Jereb, M

Zupan, M

Stavber, S

机构：

[1] Univ Ljubljana, Dept Chem, Fac Chem & Chem Technol, Ljubljana 1000, Slovenia

[2] Jozef Stefan Inst, Ljubljana 1000, Slovenia

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 22期

关键词：

D O I：

10.1039/b409919b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Efficient hydrogen peroxide enhanced iodofunctionalisation of ketones, 1,3-dicarbonyl derivatives and activated aromatic molecules using elemental iodine in water is achieved, whereas alkynes were stereoselectively converted into (E)- 1,2-diiodoalkenes.

引用

收藏

页码：2614 / 2615

页数：2

相关论文

共 19 条

[1] A new, environment friendly protocol for iodination of electron-rich aromatic compounds [J].

Adimurthy, S ;

Ramachandraiah, G ;

Ghosh, PK ;

Bedekar, AV .

TETRAHEDRON LETTERS, 2003, 44 (27) :5099-5101

[2]

[Anonymous], METAL CATALYSED CROS

[3] Reaction of alkenes with hydrogen peroxide and sodium iodide:: A nonenzymatic biogenic-like approach to iodohydrins [J].

Barluenga, J ;

Marco-Arias, M ;

González-Bobes, F ;

Ballesteros, A ;

González, JM .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (07) :1677-1682

[4] STEREOSELECTIVE BIFUNCTIONALIZATION OF ALKYNES BY MEANS OF THE MERCURY(II) SALT IODINE COMBINATION [J].

BARLUENGA, J ;

MARTINEZGALLO, JM ;

NAJERA, C ;

YUS, M .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1987, (05) :1017-1019

[5] An efficient, catalytic, aerobic, oxidative iodination of arenes using the H5PV2Mo10O40 polyoxometalate as catalyst [J].

Branytska, OV ;

Neumann, R .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (24) :9510-9512

[6] Supramolecular assemblies as promoters of iodohydrin formation [J].

Cerritelli, S ;

Chiarini, M ;

Cerichelli, G ;

Capone, M ;

Marsili, M .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2004, 2004 (03) :623-630

[7]

Clark J. H., 2008, Handbook of Green Chemistry Technology

[8] Control of the iodination reaction on activated aromatic residues in peptides [J].

Espuña, G ;

Arsequell, G ;

Valencia, G ;

Barluenga, J ;

Pérez, M ;

González, JM .

CHEMICAL COMMUNICATIONS, 2000, (14) :1307-1308

[9] STEREOCHEMISTRY OF IODINE ADDITION TO ACETYLENES [J].

HOLLINS, RA ;

CAMPOS, MPA .

JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (22) :3931-3934

[10] Development of novel Lewis acid catalysts for selective organic reactions in aqueous media [J].

Kobayashi, S ;

Manabe, K .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (04) :209-217