Negative ion formation following inner-shell photoexcitation in CO2 studied by velocity imaging spectroscopy

被引:6
|
作者
Hikosaka, Y. [1 ]
Kaneyasu, T.
Tamenori, Y.
Shigemasa, E.
机构
[1] UVSOR Facil, Inst Mol Sci, Okazaki, Aichi 4448585, Japan
[2] Japan Synchrotron Radiat Res Inst, Sayo 6795198, Japan
基金
日本学术振兴会;
关键词
negative fragment ion; CO2; imaging technique; inner-shell region;
D O I
10.1016/j.elspec.2006.11.024
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
The imaging technique has been applied to the negative fragment ion observation in the vicinity of the C1s and O1s ionization thresholds of CO2. The O- yield curves obtained exhibit, as well as the sigma* and Rydberg states bellow the ionization thresholds, doubly excited states above the thresholds. Anisotropic O- emissions with respect to the electric vector are seen on the images observed at the core-excited states, reflecting the symmetries of the states. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:284 / 288
页数:5
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