Excess molar volumes of (octane+1-chlorobutane) at temperatures between 298.15 and 328.15 K and at pressures up to 40 MPa

被引:19
作者
Morávková, L [1 ]
Linek, J [1 ]
机构
[1] Acad Sci Czech Republ, Inst Chem Proc Fundamentals, E Hala Lab Thermodynam, CR-16502 Prague 6, Czech Republic
关键词
octane; 1-chlorobutane; binary mixture; density; excess volume; high pressure; elevated temperature;
D O I
10.1016/S0021-9614(02)00307-5
中图分类号
O414.1 [热力学];
学科分类号
摘要
The (p, V, T) behaviour of (octane + I-chlorobutane) was measured at the temperatures (298.15, 308.15, 318.15, and 328.15)K and over the pressure range (0.1 to 40 MPa) with an accuracy in density of +/-1 (.) 10(-4) g (.) cm(-3). An apparatus for (p, V-m, T) measurements of liquids and liquid mixtures whose main part is a high-pressure vibrating-tube densimeter working in a static mode was used for the measurements. Excess molar volumes were calculated from the data and fitted to the Redlich-Kister equation. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:113 / 121
页数:9
相关论文
共 8 条
[1]  
[Anonymous], 1982, PROPERTIES WATER STE
[2]  
Kovács É, 2001, J CHEM THERMODYN, V33, P33
[3]   VOLUME RATIOS (V(P)/V(0.1 MPA)) FOR NORMAL-HEPTANE AT TEMPERATURES FROM 278-K TO 338-K FOR PRESSURES UP TO 400 MPA [J].
MALHOTRA, R ;
WOOLF, LA .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1991, 23 (01) :49-57
[4]   Temperature dependence of the excess molar volume of (octane+1-chloroalkane) [J].
Morávková, L ;
Linek, J .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2002, 34 (09) :1407-1415
[5]   Excess molar volumes of (heptane+1-chloropentane) at elevated temperatures and high pressures [J].
Morávková, L ;
Aim, K ;
Linek, J .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2002, 34 (09) :1377-1386
[6]   Temperature dependence of the excess molar volume of (heptane+1-chloroalkane) [J].
Morávková, L ;
Linek, J .
JOURNAL OF CHEMICAL THERMODYNAMICS, 2002, 34 (09) :1387-1395
[7]  
RIDDICK A, 1986, PHYSICAL PROPERTIES, V2
[8]  
Timmermans J., 1950, Physico-chemical constants of pure organic compounds, VI