A novel organolead(II) species, the plumbacycloalkane derivative [CH2SiMe2C(SiMe3)2PbC(SiMe3)2SiMe2CH2]

被引：39

作者：

Eaborn, C ^{[1
]}

Ganicz, T ^{[1
]}

Hitchcock, PB ^{[1
]}

Smith, JD ^{[1
]}

Sozerli, SE ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 26期

关键词：

D O I：

10.1021/om9708337

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title lead(II) derivative was obtained as dark blue crystals by treatment of PbCl2 with [Li(TMEDA)(2)][CH2SiMe2C(SiMe3)(2)LiC(SiMe3)(2)SiMe2CH2] (TMEDA = N,N,N',N'-tetramethylethylenediamine) in tetrahydrofuran and its structure determined by X-ray diffraction. The compound is in. effect the first dialkylead(II) species to be structurally characterized. The C-Pb-C angle is 117.1(2)degrees. Analogous treatment of SnCl2 yielded a yellow solid, which was judged from spectroscopic data to be the TMEDA complex of the analogous stannacycloalkane.

引用

页码：5621 / 5622

页数：2

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