A novel organolead(II) species, the plumbacycloalkane derivative [CH2SiMe2C(SiMe3)2PbC(SiMe3)2SiMe2CH2]

被引：39

作者：

Eaborn, C ^{[1
]}

Ganicz, T ^{[1
]}

Hitchcock, PB ^{[1
]}

Smith, JD ^{[1
]}

Sozerli, SE ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 26期

关键词：

D O I：

10.1021/om9708337

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title lead(II) derivative was obtained as dark blue crystals by treatment of PbCl2 with [Li(TMEDA)(2)][CH2SiMe2C(SiMe3)(2)LiC(SiMe3)(2)SiMe2CH2] (TMEDA = N,N,N',N'-tetramethylethylenediamine) in tetrahydrofuran and its structure determined by X-ray diffraction. The compound is in. effect the first dialkylead(II) species to be structurally characterized. The C-Pb-C angle is 117.1(2)degrees. Analogous treatment of SnCl2 yielded a yellow solid, which was judged from spectroscopic data to be the TMEDA complex of the analogous stannacycloalkane.

引用

页码：5621 / 5622

页数：2

共 50 条

[1] Disproportionation of Sn(ii){CH(SiMe3)2}2 to Sn(iii){CH(SiMe3)2}3 and Sn(i){CH(SiMe3)2}: characterization of the Sn(i) product
Mears, Kristian L.
Ruiz, Bronson
Nguyen, Gia-Ann
Zou, Wenxing
Fettinger, James C.
Power, Philip P.
CHEMICAL COMMUNICATIONS, 2023, 59 (42) : 6399 - 6402
[2] The Bis Metallacyclic Anion [U(N{SiMe3}2)(CH2SiMe2N{SiMe3})2]-
Benaud, Olivier
Berthet, Jean-Claude
Thuery, Pierre
Ephritikhine, Michel
INORGANIC CHEMISTRY, 2010, 49 (17) : 8117 - 8130
[3] Syntheses and structures of lithium cyanocuprates containing the C(SiMe3)3, C(SiMe3)2 (SiMe2NMe2) and C(SiMe3)(SiMe2OMe)2 groups
Eaborn, C
El-Hamruni, SM
Hill, MS
Hitchcock, PB
Smith, JD
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (21): : 3975 - 3979
[4] Novel chelated diorganolithate ion [CH(2)SiMe(2)C(SiMe(3))(2)LiC(SiMe(3))(2)SiMe(2)CH(2)](-) and highly crowded chelated organomercury compound [CH(2)SiMe(2)C(SiMe(3))(2)HgC(SiMe(3))(2)SiMe(2)CH(2)]
Eaborn, C
Lu, ZR
Hitchcock, PB
Smith, JD
ORGANOMETALLICS, 1996, 15 (06) : 1651 - 1655
[5] THE REACTION OF SN[CH(SIME3)2]2 WITH ETHYNE - FORMATION OF (HCC)SN[CH-(SIME3)2]2(MU-TRANS-CH=CH)SN[CH-(SIME3)2]2(CH=CH2)
PLUTA, C
PORSCHKE, KR
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 453 (02) : C11 - C12
[6] Attachment of the bulky bidentate ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C to K, Zn, Sn, and Yb.: Crystal structures of LnMC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2CMLn (MLn = K(C6H6)2, K(THF)2, SnCl3, or SnMe2Cl) and CH2SiMe2C(SiMe3)2ZnC(SiMe3)2SiMe2CH2 (THF = tetrahydrofuran)
Eaborn, C
Hill, MS
Hitchcock, PB
Smith, JD
Zhang, SB
Ganicz, T
ORGANOMETALLICS, 1999, 18 (12) : 2342 - 2348
[7] DESILYLATION AND CYCLOMETALLATION REACTIONS OF DIPHENYL(TRIS(TRIMETHYLSILYL)METHYL) PHOSPHINE WITH PLATINUM(II) COMPOUNDS - CRYSTAL-STRUCTURE OF TRANS-[PTCLPPH2C(SIME3)2SIME2CH2(PPH2CH(SIME3)2)]
ALJUAID, SS
EABORN, C
HITCHCOCK, PB
SMITH, JD
ZANOTTO, L
KAPOOR, PN
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 394 (1-3) : 69 - 75
[8] Oxidative addition to a monomeric stannylene to give four-coordinate tin compounds containing the bulky bidentate ligand C(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2C.: Crystal structures of CH2Me2Si(Me3Si)2CSnC(SiMe3)2SiMe2CH2, CH2Me2Si(Me3Si)2CSnMe(OCOCF3)C(SiMe3)2SiMe2CH2, and (CF3COO)2MeSnC(SiMe3)2SiMe2CH2CH2Me2Si(Me3Si)2CSnMe(OCOCF3)2
Eaborn, C
Hill, MS
Hitchcock, PB
Patel, D
Smith, JD
Zhang, SB
ORGANOMETALLICS, 2000, 19 (01) : 49 - 53
[9] SYNTHESIS AND MOLECULAR-STRUCTURE OF A BIS[DI(ALKYL)ALANYL]METHANE - (CH(SIME3)2)2AL-CH2-AL(CH(SIME3)2)2
LAYH, M
UHL, W
POLYHEDRON, 1990, 9 (2-3) : 277 - 282
[10] Synthesis and structures of crystalline lithium, sodium, potassium, and magnesium silylmethyls derived from the ligands [CH(SiMe3){SiMe3-n(OMe)n}]-(n=1, 2), [CH(SiMe2OMe)2]-, and. [CH(SiMe3)(SiMe2Ph)]-
Antolini, F
Hitchcock, PB
Lappert, MF
Wei, HX
ORGANOMETALLICS, 2003, 22 (12) : 2505 - 2516

← 1 2 3 4 5 →