Regulation and control of polymer network deformation in reverse-mode polymer-stabilised cholesteric texture

被引:10
作者
Chu, Yutian [1 ]
Yin, Zhiping [1 ]
Sha, Junqing [1 ]
Xu, Chao [1 ]
Zhang, Guobing [1 ,2 ]
Lv, Guoqiang [1 ]
Qiu, Longzhen [1 ,2 ]
Lu, Hongbo [1 ,2 ]
机构
[1] Hefei Univ Technol, Key Lab Special Display Technol, Minist Educ,Acad Optoelect Technol, Natl Engn Lab Special Display Technol,State Key L, Hefei, Peoples R China
[2] Hefei Univ Technol, Sch Chem & Chem Engn, Key Lab Adv Funct Mat & Devices, Hefei, Anhui, Peoples R China
基金
国家高技术研究发展计划(863计划); 中国国家自然科学基金;
关键词
Polymer-stabilised cholesteric texture; polymer network deformation; electro-optical properties; hysteresis; LIQUID-CRYSTALS; ELECTROOPTICAL PROPERTIES; MORPHOLOGY; PERFORMANCE; PROPERTY;
D O I
10.1080/02678292.2016.1230895
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
By simulating the dynamic response processes of reverse-mode polymer-stabilised cholesteric texture (PSCT) via double exponential rise/decay model, the deformation of polymer networks were quantitatively characterised. The polymer network deformation is shown to be controlled by regulating monomer concentration and the applied electric field. Increased monomer concentration facilitates the production of polymer fibrils of a higher polymer molecular weight while suppressing distortion of the polymer network. Decreased polymer network deformation assists in the decrease of the undesired hysteresis phenomenon while also demonstrating a shorter field-off response time of PSCT; however, the trade-off is increased operation voltage and decreased contrast ratio. The observed results provide useful guidelines for future PSCT material and device optimisations. [GRAPHICS] .
引用
收藏
页码:688 / 694
页数:7
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