Exploring the reactivity of a ruthenium complex in the metathesis of biorenewable feedstocks to generate value-added chemicals

被引：21

作者：

Alexander, Kathryn A. ^{[1
]}

Paulhus, Emily A. ^{[1
]}

Lazarus, Gillian M. L. ^{[1
]}

Leadbeater, Nicholas E. ^{[1
]}

机构：

[1] Univ Connecticut, Dept Chem, 55 North Eagleville Rd, Storrs, CT 06269 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2016年 / 812卷

基金：

美国国家科学基金会;

关键词：

Metathesis; Ruthenium; Biorenewable; N-heterocyclic carbene; Valorization; RING-CLOSING METATHESIS; OLEFIN CROSS-METATHESIS; FATTY-ACID ESTERS; CONTINUOUS-FLOW; METHYL OLEATE; CATALYSTS; ETHENOLYSIS; EFFICIENT; CHEMISTRY; OILS;

D O I：

10.1016/j.jorganchem.2015.09.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tricyclohexylphosphine[4,5-dimethyl-1,3-bis(2,4,6-trimethylphenypimidazol-2-ylidene][2-thienylmeth ylene]ruthenium(II) dichloride proves active for the ring-closing metathesis of linalool and citronellene, the self-metathesis of eugenol, and to some extent the ethenolysis of methyl oleate. Microwave heating and continuous-flow processing have been used as tools for performing the reactions. For the ring closing metathesis reactions, transition from batch to flow processing for scale-up of the reaction is possible but it proves problematic in the case of cross-metathesis. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：74 / 80

页数：7

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