Synthesis, crystal structure and electrochemistry of biferrocene palladium complex

被引：0

作者：

Chen, G ^{[1
]}

Ou, SJ ^{[1
]}

Bai, ZP ^{[1
]}

Han, G ^{[1
]}

Duan, CY ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2003年 / 19卷 / 05期

关键词：

ferrocene; cis-configuration; self-assembly; C-H center dot center dot center dot pi interaction; electrochemistry;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new supramolecular cyclohexane-like structure [PdL2](6)(HL = acetylferrocenyl thiosemicarbazone) has been constructed by self-assembly of ferrocene moieties via C - H...pi interactions. The palladium (II) atom is coordinated in a distorted square-planar cis-configuration in which two ferrocene-containing ligands positioned on the same side. Each ferrocene moieties interacts with symmetry-related species to form a two dimensions supramolecular network. Electrochemical measurements of [PdL2], [NiL2] and [ZnL2] compounds indicate that the square planar configuration of the Ni (II) and Pd (II) moieties, can effectively transmit the redox effects of the ferrocene moieties.

引用

页码：501 / 505

页数：5

共 25 条

[1] CRYSTALLOGRAPHIC STUDY OF SOLID BENZENE BY NEUTRON DIFFRACTION [J].

BACON, GE ;

CURRY, NA ;

WILSON, SA .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1964, 279 (1376) :98-+

[2]

BERSTERN T, 1968, ACTA CRYSTALLOGR B, V24, P1546

[3]

BIRADHA K, 1989, J AM CHEM SOC CHEM C, P621

[4] BINUCLEAR COMPLEXES OF RUTHENIUM AMMINES [J].

CREUTZ, C ;

TAUBE, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (04) :1086-1094

[5] Supramolecular motifs:: sextuple aryl embraces in crystalline [M(2,2′-bipy)3] and related complexes [J].

Dance, I ;

Scudder, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (08) :1341-1350

[6] Concerted supramolecular moths: Linear columns and zigzag chains of multiple phenyl embraces involving Ph(4)P(+) cations in crystals [J].

Dance, I ;

Scudder, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (19) :3755-3769

[7] Designer crystals: intermolecular interactions, network structures and supramolecular synthons [J].

Desiraju, GR .

CHEMICAL COMMUNICATIONS, 1997, (16) :1475-1482

[8] SUPRAMOLECULAR SYNTHONS IN CRYSTAL ENGINEERING - A NEW ORGANIC-SYNTHESIS [J].

DESIRAJU, GR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (21) :2311-2327

[9] Syntheses, electrochemistry and crystal structure studies of novel cis-configuration biferrocene trinuclear complexes [J].

Duan, CY ;

Tian, YP ;

Liu, ZH ;

You, XZ ;

Mak, TCW .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 570 (02) :155-162

[10]

FAN CJ, 2000, NEW J CHEM, V24, P697

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