Synthesis and photocatalytic properties of hierarchical metal nanoparticles/ZnO thin films hetero nanostructures assisted by diblock copolymer inverse micellar nanotemplates

被引:37
作者
Jang, Yoon Hee [1 ]
Kochuveedu, Saji Thomas [1 ]
Cha, Min-Ah [1 ]
Jang, Yu Jin [1 ]
Lee, Ji Yong [1 ]
Lee, Jieun [1 ]
Lee, Juyon [1 ]
Kim, Jooyong [2 ]
Ryu, Du Yeol [3 ,4 ]
Kim, Dong Ha [1 ]
机构
[1] Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 120750, South Korea
[2] Soongsil Univ, Dept Organ Mat & Fiber Engn, Seoul 156743, South Korea
[3] Yonsei Univ, Dept Chem Engn, Seoul 120749, South Korea
[4] Yonsei Univ, Act Polymer Ctr Pattern Integrat, Seoul 120749, South Korea
基金
新加坡国家研究基金会;
关键词
Hierarchical nanostructures; ZnO thin film; Self-assembly; Block copolymer micelle; Sol-gel; POLYCRYSTALLINE ZNO/TIO2 SYSTEMS; ZNO NANOPARTICLES; ORDERED ARRAYS; DEGRADATION; SURFACE; TIO2; PHOTODEGRADATION; EFFICIENCY;
D O I
10.1016/j.jcis.2010.01.040
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Metal dot-on-ZnO type hierarchical nanostructures composed of ordered arrays of noble metal nanoparticles with controlled areal density, prepared from poly(styrene-block-vinyl pyridine) diblock copolymer inverse micelles loaded with metal precursors, on sol-gel process based similar to 48 nm thick ZnO thin films exhibit enhanced photocatalytic activities compared with pure ZnO thin films in terms of photodegradation of methylene blue. (C) 2010 Elsevier Inc. All rights reserved.
引用
收藏
页码:125 / 130
页数:6
相关论文
共 33 条
[1]   Block copolymer micelle nanolithography [J].
Glass, R ;
Möller, M ;
Spatz, JP .
NANOTECHNOLOGY, 2003, 14 (10) :1153-1160
[2]   Micro-nanostructured interfaces fabricated by the use of inorganic block copolymer micellar monolayers as negative resist for electron-beam lithography [J].
Glass, R ;
Arnold, M ;
Blümmel, J ;
Küller, A ;
Möller, M ;
Spatz, JP .
ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (07) :569-575
[3]   Photocatalytic degradation of organic contaminants in water by ZnO nanoparticles: Revisited [J].
Hariharan, C. .
APPLIED CATALYSIS A-GENERAL, 2006, 304 (01) :55-61
[4]   Ag-ZnO catalysts for UV-photodegradation of methylene blue [J].
Height, MJ ;
Pratsinis, SE ;
Mekasuwandumrong, O ;
Praserthdam, P .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 63 (3-4) :305-312
[5]   Room-temperature ultraviolet nanowire nanolasers [J].
Huang, MH ;
Mao, S ;
Feick, H ;
Yan, HQ ;
Wu, YY ;
Kind, H ;
Weber, E ;
Russo, R ;
Yang, PD .
SCIENCE, 2001, 292 (5523) :1897-1899
[6]   Catalytic activity of supported au nanoparticles deposited from block copolymer micelles [J].
Jaramillo, TF ;
Baeck, SH ;
Roldan Cuenya, B ;
McFarland, EW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (24) :7148-7149
[7]   On the synergistic coupling properties of composite CdS/TiO2 nanoparticle arrays confined in nanopatterned hybrid thin films [J].
Kannaiyan, Dinakaran ;
Kim, Eunhye ;
Won, Nayoun ;
Kim, Kang Wook ;
Jang, Yoon Hee ;
Cha, Min-Ah ;
Ryu, Du Yeol ;
Kim, Sungjee ;
Kim, Dong Ha .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (04) :677-682
[8]   Micellar nanoreactors -: Preparation and characterization of hexagonally ordered arrays of metallic nanodots [J].
Kästle, G ;
Boyen, HG ;
Weigl, F ;
Lengl, G ;
Herzog, T ;
Ziemann, P ;
Riethmüller, S ;
Mayer, O ;
Hartmann, C ;
Spatz, JP ;
Möller, M ;
Ozawa, M ;
Banhart, F ;
Garnier, MG ;
Oelhafen, P .
ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (11) :853-861
[9]   Photocatalytic degradation of selected s-triazine herbicides and organophosphorus insecticides over aqueous TiO2 suspensions [J].
Konstantinou, IK ;
Sakellarides, TM ;
Sakkas, VA ;
Albanis, TA .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2001, 35 (02) :398-405
[10]  
Kwon YT, 2000, J CATAL, V191, P192