Novel Electrochemical Sensor for Highly Sensitive Detection of Adenine Based on Vanadium Pentoxide Nanofibers Modified Screen Printed Carbon Electrode

被引:1
作者
Annalakshmi, Muthaiah [1 ]
Sangili, Arumugam [1 ]
Chen, Shen-Ming [1 ]
Chen, Tse-Wei [1 ]
Liu, Xiaoheng [2 ]
Selvam, V. [3 ]
机构
[1] Natl Taipei Univ Technol, Dept Chem Engn & Biotechnol, Electroanalyt & Bioelectrochem Lab, 1,Sect 3,Chung Hsiao East Rd, Taipei 106, Taiwan
[2] Nanjing Univ Sci & Technol, Educ Minist Soft Chem & Funct Mat, Key Lab, Nanjing 210094, Jiangsu, Peoples R China
[3] MDT Hindu Coll Pettai, Tirunelveli 627010, Tamil Nadu, India
关键词
Vanadium pentoxide; nano-fibers; Adenine; electro-oxidation; human urine sample; VOLTAMMETRIC DETERMINATION; GLUCOSE-OXIDASE; COMPOSITE FILM; GUANINE; NANOTUBES; NANOCOMPOSITE; PERFORMANCE; DOPAMINE; THYMINE; PURINE;
D O I
10.20964/2018.07.41
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Herein, we report a simplistic approach to prepare vanadium pentoxide nanofibers (V2O5 NFs) using simple hydrothermal method. The as-synthesized material was confirmed by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX) techniques, scanning electron microscopy (SEM). In addition, V2O5 NFs was used as an electrocatalytic performance towards the electro-oxidation of Adenine. Interestingly, V2O5 NFs modified electrode (V2O5 NFs/SPCE) showed an excellent electrocatalytic activity towards Adenine with lower detection limit (0.013 mu M), wide linear ranges (0.5 to 512 mu M) and the higher sensitivity about 8.5333 mu A mu M-1 cm(-2). Furthermore, V2O5 NFs/SPCE was also demonstrated good recovery even in real human urine samples. This study opens a new window for the trace level identification of biological molecules in real samples.
引用
收藏
页码:6218 / 6228
页数:11
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