Simple and Efficient Method for Acetylation of Alcohols, Phenols, Amines, and Thiols Using Anhydrous NiCl2 Under Solvent-Free Conditions

被引：22

作者：

Meshram, Gangadhar ^{[1
]}

Patil, Vishvanath D. ^{[1
]}

机构：

[1] Univ Mumbai, Dept Chem, Bombay, Maharashtra, India

来源：

SYNTHETIC COMMUNICATIONS | 2009年 / 39卷 / 24期

关键词：

Acetic anhydride; acetylation; anhydrous NiCl2; solvent-free; ACTIVE ACYLATION CATALYST; HIGHLY EFFICIENT; ACETIC-ANHYDRIDE; ACID ANHYDRIDES; LEWIS-ACID; TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE; SCANDIUM TRIFLUOROMETHANESULFONATE; MONTMORILLONITE K-10; VERSATILE CATALYST; O-ACETYLATION;

D O I：

10.1080/00397910902906529

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Solvent-free acetylation of alcohols, phenols, amines, and thiols with acetic anhydride (Ac2O) in the presence of 0.1 mol% (13 mg) anhydrous NiCl2, an inexpensive and easily available catalyst, is described. Excellent yields, short reaction time, and mild reaction conditions are important features of this method.

引用

页码：4384 / 4395

页数：12

共 50 条

[21] Acetylation of Phenols, Anilines, and Thiols Using Silica Sulfuric Acid under Solvent-Free Conditions
Habibi, Davood
Rahmani, Payam
Akbaripanah, Ziba
JOURNAL OF CHEMISTRY, 2013, 2013
[22] N,N'-Diiodo-N,N'-1,2-ethanediylbis(p-toluenesulfonamide) as an Efficient Catalyst for Acetylation of Alcohols, Phenols, Amines, and Thiols Under Solvent-Free Conditions
Ghorbani-Vaghei, Ramin
Toghraei-Semiromi, Zahra
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2010, 185 (08) : 1701 - 1707
[23] Pentafluorophenylammonium Triflate as a Mild and New Organocatalyst for Acylation of Alcohols, Phenols, and Amines Under Solvent-Free Condition
Khaksar, Samad
Zakeri, Hasan
COMBINATORIAL CHEMISTRY & HIGH THROUGHPUT SCREENING, 2012, 15 (07) : 576 - 579
[24] Spinel-type zinc aluminate (ZnAl2O4) nanoparticles prepared by the co-precipitation method: A novel, green and recyclable heterogeneous catalyst for the acetylation of amines, alcohols and phenols under solvent-free conditions
Farhadi, Saeid
Panahandehjoo, Somayeh
APPLIED CATALYSIS A-GENERAL, 2010, 382 (02) : 293 - 302
[25] Lewis basic ionic liquid as an efficient and facile catalyst for acetylation of alcohols, phenols, and amines under solvent-free conditions
Li Ji
Chao Qian
Xin-zhi Chen
Monatshefte für Chemie - Chemical Monthly, 2013, 144 : 369 - 374
[26] Acetylation of alcohols and phenols by zinc zirconium phosphate as an efficient heterogeneous catalyst under solvent-free conditions
Abdol Reza Hajipour
Hirbod Karimi
Morteza Karimzadeh
Monatshefte für Chemie - Chemical Monthly, 2014, 145 : 1461 - 1472
[27] Fe3O4@SiO2/Schiff Base Complex of Co(II) as an Efficient Lewis Acid Nanocatalyst for Acetylation of Alcohols and Phenols Under Solvent-Free Conditions
Mohsen, Esmaeilpour
Reza, Sardarian Ali
Hamed, Hassannezhad
IRANIAN JOURNAL OF SCIENCE AND TECHNOLOGY TRANSACTION A-SCIENCE, 2017, 41 (A3): : 735 - 747
[28] ZnAl2O4@SiO2 nanocomposite catalyst for the acetylation of alcohols, phenols and amines with acetic anhydride under solvent-free conditions
Farhadi, Saeed
Jahanara, Kosar
CHINESE JOURNAL OF CATALYSIS, 2014, 35 (03) : 368 - 375
[29] The zinc chromium ferrite magnetic nanoparticles ZnCrFeO4: An efficient catalyst for acetylation of alcohols, phenols and amines under solvent-free conditions
Rasouli, Nahid
Movahedi, Maryam
Naeini, Elaheh Aghabeikzadeh
IRANIAN CHEMICAL COMMUNICATION, 2018, 6 (02) : 169 - 179
[30] Iodine Supported on 3-Aminopropyl Silica Gel as Efficient Catalyst for Acetylation of Alcohols under Solvent-free Conditions
Mahdavi, Hossein
Ghaemy, Mosa
Zeraatpisheh, Fatemeh
CHINESE JOURNAL OF CHEMISTRY, 2009, 27 (02) : 347 - 352

← 1 2 3 4 5 →