A physicochemical investigation of ionic liquid mixtures

被引：173

作者：

Clough, Matthew T. ^{[1
]}

Crick, Colin R. ^{[1
]}

Grasvik, John ^{[1
]}

Hunt, Patricia A. ^{[1
]}

Niedermeyer, Heiko ^{[1
]}

Welton, Tom ^{[1
]}

Whitaker, Oliver P. ^{[2
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] Tonbridge Sch, Tonbridge TN9 1JP, Kent, England

来源：

CHEMICAL SCIENCE | 2015年 / 6卷 / 02期

关键词：

SOLVATOCHROMIC COMPARISON METHOD; THERMAL-PROPERTIES; BINARY-MIXTURES; AB-INITIO; ANION; SALT; RAMAN; DECOMPOSITION; DEGRADATION; STABILITY;

D O I：

10.1039/c4sc02931c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ionic liquids have earned the reputation of being 'designer solvents' due to the wide range of accessible properties and the degree of fine-tuning afforded by varying the constituent ions. Mixtures of ionic liquids offer the opportunity for further fine-tuning of properties. A broad selection of common ionic liquid cations and anions are employed to create a sample of binary and reciprocal binary ionic liquid mixtures, which are analysed and described in this paper. Physical properties such as the conductivity, viscosity, density and phase behaviour (glass transition temperatures) are examined. In addition, thermal stabilities of the mixtures are evaluated. The physical properties examined for these formulations are found to generally adhere remarkably closely to ideal mixing laws, with a few consistent exceptions, allowing for the facile prediction and control of properties of ionic liquid mixtures.

引用

页码：1101 / 1114

页数：14

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