Infrared and Raman spectroscopic investigations of xMnO (100-x)[As2O3 TeO2] glass system

被引:12
作者
Ardelean, I. [2 ]
Lupsor, Simona [2 ]
Rusu, Dorina [1 ]
机构
[1] Res Inst Analyt Instrumentat, Cluj Napoca 400293, Romania
[2] Univ Babes Bolyai, Fac Phys, Cluj Napoca 400084, Romania
关键词
As2O3 center dot TeO2 glass matrix; Manganese ions; FT-IR; Raman; PHYSICAL-PROPERTIES; PBO-AS2O3; GLASSES; OXIDE GLASSES; IONS;
D O I
10.1016/j.physb.2010.02.022
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
xMnO center dot (100-x)[As2O3 center dot TeO2] glass system, with 0 <= x <= 50 mol %, was prepared and investigated by FT-IR and Raman spectroscopies in order to determine its structure and the changes induced by the increasing of MnO content. The results offered by FT-IR and Raman spectroscopies suggest a structure formed by AsO3, TeO4 tbp and TeO3 tp units. The presence of MnO2 units was confirmed by FT-IR spectra only for high concentration of MnO. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:2259 / 2262
页数:4
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