Molybdatophosphoric acid as an efficient catalyst for the catalytic and chemoselective oxidation of sulfides to sulfoxides using urea hydrogen peroxide as a commercially available oxidant

被引：16

作者：

Hasaninejad, Alireza ^{[2
]}

Zolfigol, Mohammad Ali ^{[3
]}

Chehardoli, Gholamabbas ^{[1
]}

Mokhlesi, Mohammad ^{[3
]}

机构：

[1] Hamedan Univ Med Sci, Sch Pharm, Hamadan 65178, Iran

[2] Persian Golf Univ, Fac Sci, Dept Chem, Bushehr 75169, Iran

[3] Bu Ali Sina Univ, Fac Chem, Hamadan 6517838683, Iran

来源：

JOURNAL OF THE SERBIAN CHEMICAL SOCIETY | 2010年 / 75卷 / 03期

关键词：

molybdatophosphoric acid; urea hydrogen peroxide (UHF); chemoselective; oxidation; sulfides; sulfoxides; SELECTIVE OXIDATION; CARBONYL-COMPOUNDS; ALUMINUM-CHLORIDE; AEROBIC OXIDATION; PERIODIC ACID; SILICA-GEL; SULFONES; ALCOHOLS; EPOXIDATION; COMPLEXES;

D O I：

10.2298/JSC081210001H

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An efficient procedure for the chemoselective oxidation of alkyl (aryl) sulfides to the corresponding sulfoxides using urea hydrogen peroxide (UHF) in the presence of a catalytic amount of molybdatophosphoric acid at room temperature is described. The advantages of described method are: generality, high yield and chemoselectivity, short reaction time, low cost and compliment with green chemistry protocols.

引用

页码：307 / 316

页数：10

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