Synthesis, Crystal Structure, and Luminescent Property of One Cadmium(II) Coordination Polymer with Mixed Tetrahydrofuran-2,3,4,5-tetracarboxyate and 2,2'-Bipyridyl-like Ligands

被引：0

作者：

Liu, Chun-Sen ^{[1
]}

Hu, Min ^{[1
]}

Zhang, Qiang ^{[1
]}

Zhou, Li-Ming ^{[1
]}

Fang, Shao-Ming ^{[1
]}

机构：

[1] Zhengzhou Univ Light Ind, Henan Prov Key Lab Surface & Interface Sci, Zhengzhou 450002, Henan, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2010年 / 40卷 / 08期

关键词：

3-(2-pyridyl)pyrazole; luminescence; Cd(II) complex; tetrahydrofuran-2; 3; 4; 5-tetracarboxylate; METAL-ORGANIC FRAMEWORKS; ARCHITECTURES; CARBOXYLATE; COMPLEXES; ACID; TETRANUCLEAR;

D O I：

10.1080/15533174.2010.503220

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A one-dimensional (1-D) coordination polymer, {[Cd2L (pp)2 (H2O)](H2O)2.5}n (L = tetrahydrofuran-2,3,4,5-tetracarboxylate and pp = 3-(2-pyridyl)pyrazole) was synthesized and structurally characterized by single crystal X-ray diffraction analysis. This complex belongs to monoclinic system with space group P2(1)/n. Adjacent dinuclear nodes are alternately bridged by L ligands to form a 1-D ribbon-shaped structure. In addition, such 1-D chains above are further linked by interchain OHO and CHO hydrogen-bonding interactions along the different crystallographic directions, generating an overall three-dimensional (3D) supramolecular framework. Studies on photoluminescent properties of this complex show the solid-state blue emission originating from an intraligand * transition of chelating pp co-ligand.

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页码：548 / 555

页数：8

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