Solvent effects on hydrogen bonding

被引：193
|
作者：
Cook, Joanne L.
Hunter, Christopher A. [1 ]
Low, Caroline M. R.
Perez-Velasco, Alejandro
Vinter, Jeremy G.
机构：
[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England
[2] James Black Fdn, London SE24 9JE, England
[3] Ctesset Biomol Discovery, Letchworth SG6 4ET, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 20期
基金：
英国工程与自然科学研究理事会;
关键词：
hydrogen bonds; molecular recognition; NMR spectroscopy; noncovalent interactions; solvent effects;
D O I：
10.1002/anie.200604966
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Graph Presented) Environmental issues: The stability of the 1:1 hydrogen-bonded complex formed between tri-n-butylphosphine oxide (A) and perfluoro-tert-butyl alcohol (DH) has been measured in a range of solvents. The association constants (Kexpt) span five orders of magnitude and are predicted (Kpred) remarkably accurately by a simple solvent competition model (see picture). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：3706 / 3709
页数：4
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