Preparation of PVDF-co-PAAm membrane with robust antifouling, and antibacterial performance by blending with magnetic graphene oxide

被引:17
作者
Aldawsari, Abdullah M. [1 ]
Hassan, Hassan M. A. [2 ]
Alrashidi, Abdulelah Nashmi [2 ]
Alsohaimi, Ibrahim Hotan [2 ]
Alsohaimi, Hotan
Moustafa, Shaima M. N. [3 ]
Youssef, Hany M. [1 ]
Hamdi, Raghda [1 ]
Azzam, Maged A. [1 ]
机构
[1] Prince Sattam Bin Abdulaziz Univ, Coll Sci & Humanities, Dept Chem, Al kharj, Saudi Arabia
[2] Jouf Univ, Coll Sci, Chem Dept, Sakaka 2014, Saudi Arabia
[3] Jouf Univ, Coll Sci, Biol Dept, POB 2014, Sakaka, Saudi Arabia
来源
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING | 2022年 / 10卷 / 03期
关键词
Hydrophilicity; PVDF; Graphene oxide; Antifouling performance; Antibacterial; POLY(VINYLIDENE FLUORIDE); POLY(PHENYL ACRYLATE); POLY(STYRENE-CO-ACRYLONITRILE); HYDROPHILICITY; NANOPARTICLES; CALORIMETRY; MISCIBILITY; ADSORPTION; REDUCTION;
D O I
10.1016/j.jece.2022.108093
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Ultrafiltration membranes (UF) have been utilized in a variety of industrial sectors. However, the primary challenge with UF membrane is fouling. To prevent this problem, the PVDF-co-PAAm copolymer blended with magnetic graphene oxide (MGO) was prepared using a nonsolvent induced phase separation (NIPS) approach to develop the PVDF-co-PAAm /MGO nanocomposite membrane. As a comparison, the efficiency of the membranes was assessed using four types of PVDF, PVDF-co-PAAm, PVDF-co-PAAm /GO, and PVDF-co-PAAm /MGO. The chemical structure and morphology were characterized by ATR-FTIR, XRD, FESEM, zeta-potential, and hydrophilicity. The assessment of the synthesized membranes performance was comprised permeation, antifouling, and antibacterial activities. The ATR-FTIR spectra and XRD pattern confirmed that PVDF-co-PAAm/MGO was successfully prepared. FESEM assessment confirm that the PVDF-co-PAAm/MGO membrane illustrated the ultra filtration morphology. Membrane hydrophilicity and porous homogeneity were both boosted. A 60% improve in pure water flux, 110% improve in flux recovery ratio, and 125% improve in rejection % were attained when PVDF-co-PAAm was blended with MGO. The R-r may rise from 6.05% to 39.81%, while the R-ir may decline from 53.53% to 42.16%. Additionally, the amended membrane demonstrated strong antibacterial activity, with a maximum antibacterial ratio. In conclusion, the blending of PVDF-co-PAAm with MGO might result in membranes with a robust hydrophilicity, water flux, rejection (%) and antibacterial activities.
引用
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页数:10
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