Preparation of PVDF-co-PAAm membrane with robust antifouling, and antibacterial performance by blending with magnetic graphene oxide

被引:17
作者
Aldawsari, Abdullah M. [1 ]
Hassan, Hassan M. A. [2 ]
Alrashidi, Abdulelah Nashmi [2 ]
Alsohaimi, Ibrahim Hotan [2 ]
Alsohaimi, Hotan
Moustafa, Shaima M. N. [3 ]
Youssef, Hany M. [1 ]
Hamdi, Raghda [1 ]
Azzam, Maged A. [1 ]
机构
[1] Prince Sattam Bin Abdulaziz Univ, Coll Sci & Humanities, Dept Chem, Al kharj, Saudi Arabia
[2] Jouf Univ, Coll Sci, Chem Dept, Sakaka 2014, Saudi Arabia
[3] Jouf Univ, Coll Sci, Biol Dept, POB 2014, Sakaka, Saudi Arabia
来源
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING | 2022年 / 10卷 / 03期
关键词
Hydrophilicity; PVDF; Graphene oxide; Antifouling performance; Antibacterial; POLY(VINYLIDENE FLUORIDE); POLY(PHENYL ACRYLATE); POLY(STYRENE-CO-ACRYLONITRILE); HYDROPHILICITY; NANOPARTICLES; CALORIMETRY; MISCIBILITY; ADSORPTION; REDUCTION;
D O I
10.1016/j.jece.2022.108093
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Ultrafiltration membranes (UF) have been utilized in a variety of industrial sectors. However, the primary challenge with UF membrane is fouling. To prevent this problem, the PVDF-co-PAAm copolymer blended with magnetic graphene oxide (MGO) was prepared using a nonsolvent induced phase separation (NIPS) approach to develop the PVDF-co-PAAm /MGO nanocomposite membrane. As a comparison, the efficiency of the membranes was assessed using four types of PVDF, PVDF-co-PAAm, PVDF-co-PAAm /GO, and PVDF-co-PAAm /MGO. The chemical structure and morphology were characterized by ATR-FTIR, XRD, FESEM, zeta-potential, and hydrophilicity. The assessment of the synthesized membranes performance was comprised permeation, antifouling, and antibacterial activities. The ATR-FTIR spectra and XRD pattern confirmed that PVDF-co-PAAm/MGO was successfully prepared. FESEM assessment confirm that the PVDF-co-PAAm/MGO membrane illustrated the ultra filtration morphology. Membrane hydrophilicity and porous homogeneity were both boosted. A 60% improve in pure water flux, 110% improve in flux recovery ratio, and 125% improve in rejection % were attained when PVDF-co-PAAm was blended with MGO. The R-r may rise from 6.05% to 39.81%, while the R-ir may decline from 53.53% to 42.16%. Additionally, the amended membrane demonstrated strong antibacterial activity, with a maximum antibacterial ratio. In conclusion, the blending of PVDF-co-PAAm with MGO might result in membranes with a robust hydrophilicity, water flux, rejection (%) and antibacterial activities.
引用
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页数:10
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共 46 条
[1]   Application of sulfonic acid group functionalized graphene oxide to improve hydrophilicity, permeability, and antifouling of PVDF nanocomposite ultrafiltration membranes [J].
Ayyaru, Sivasankaran ;
Ahn, Young-Ho .
JOURNAL OF MEMBRANE SCIENCE, 2017, 525 :210-219
[2]   Determination of the crystalline phases of poly(vinylidene fluoride) under different preparation conditions using differential scanning calorimetry and infrared spectroscopy [J].
Benz, M ;
Euler, WB .
JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 89 (04) :1093-1100
[3]   Preparation and characterization of novel porous PVDF-ZrO2 composite membranes [J].
Bottino, A ;
Capannelli, G ;
Comite, A .
DESALINATION, 2002, 146 (1-3) :35-40
[4]   Investigating submerged ultrafiltration (UF) and microfiltration (MF) membranes for seawater pre-treatment dedicated to total removal of undesirable micro-algae [J].
Castaing, J. -B. ;
Masse, A. ;
Pontie, M. ;
Sechet, V. ;
Haure, J. ;
Jaouen, P. .
DESALINATION, 2010, 253 (1-3) :71-77
[5]   Coating of hydrophobic hollow fiber PVDF membrane with chitosan for protection against wetting and flavor loss in osmotic distillation process [J].
Chanachai, Ampai ;
Meksup, Kittikun ;
Jiraratananon, Ratana .
SEPARATION AND PURIFICATION TECHNOLOGY, 2010, 72 (02) :217-224
[6]   Novel catalytic self-cleaning membrane with peroxymonosulfate activation for dual-function wastewater purification: Performance and mechanism [J].
Chen, Binghong ;
Hu, Xinyu ;
Wang, Jing ;
Li, Renjie ;
Shen, Liguo ;
Xu, Yanchao ;
Zhang, Meijia ;
Hong, Huachang ;
Lin, Hongjun .
JOURNAL OF CLEANER PRODUCTION, 2022, 355
[7]   Fouling resistant mixed matrix polyethersulfone membranes blended with magnetic nanoparticles: Study of magnetic field induced casting [J].
Daraei, Parisa ;
Madaeni, Sayed Siavash ;
Ghaemi, Negin ;
Khadivi, Mohammad Ali ;
Astinchap, Bandar ;
Moradian, Rostam .
SEPARATION AND PURIFICATION TECHNOLOGY, 2013, 109 :111-121
[8]   A green chemical route for synthesis of graphene supported palladium nanoparticles: A highly active and recyclable catalyst for reduction of nitrobenzene [J].
El-Hout, S. I. ;
El-Sheikh, S. M. ;
Hassan, Hassan M. A. ;
Harraz, Farid A. ;
Ibrahim, I. A. ;
El-Sharkawy, E. A. .
APPLIED CATALYSIS A-GENERAL, 2015, 503 :176-185
[9]  
Gao W, 2009, NAT CHEM, V1, P403, DOI [10.1038/NCHEM.281, 10.1038/nchem.281]
[10]   Microwave synthesis of graphene sheets supporting metal nanocrystals in aqueous and organic media [J].
Hassan, M. A. Hassan ;
Abdelsayed, Victor ;
Khder, Abd El Rahman S. ;
AbouZeid, Khaled M. ;
Terner, James ;
El-Shall, M. Samy ;
Al-Resayes, Saud I. ;
El-Azhary, Adel A. .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (23) :3832-3837