N-Heterocyclic Carbene-Main-Group Chemistry: A Rapidly Evolving Field

被引：219
作者：
Wang, Yuzhong [1 ]
Robinson, Gregory H. [1 ]
机构：
[1] Univ Georgia, Dept Chem, Athens, GA 30602 USA
来源：
INORGANIC CHEMISTRY | 2014年 / 53卷 / 22期
基金：
美国国家科学基金会;
关键词：
ELECTRON-SPIN-RESONANCE; GALLIUM TRIPLE BOND; DISILYNE RSISIR R; MOLECULAR-STRUCTURE; STRUCTURAL-CHARACTERIZATION; LEWIS-BASE; ORGANOMETALLIC CHEMISTRY; PERSISTENT PHOSPHINYL; SINGLET CARBENES; CHEMICAL-SHIFTS;
D O I：
10.1021/ic502231m
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This Award Article targets the evolving, yet surprisingly fruitful, chemistry of N-heterocyclic carbenes with low-oxidation-state main-group elements. Specifically, the chemistry of carbene-stabilized diatomic allotropes, diborenes, gallium octahedra, beryllium borohydride, and a host of related compounds will be presented. Providing a valuable historical perspective, the foundational work concerning the organometallic chemistry of gallium with sterically demanding m-terphenyl ligands from this laboratory will also be discussed.
引用
收藏
页码：11815 / 11832
页数：18
相关论文
共 194 条
  • [1] Oxidation of Carbene-Stabilized Diarsenic: Diarsene Dications and Diarsenic Radical Cations
    Abraham, Mariham Y.
    Wang, Yuzhong
    Xie, Yaoming
    Gilliard, Robert J., Jr.
    Wei, Pingrong
    Vaccaro, Brian J.
    Johnson, Michael K.
    Schaefer, Henry F., III
    Schleyer, Paul v. R.
    Robinson, Gregory H.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (07) : 2486 - 2488
  • [2] Cleavage of Carbene-Stabilized Disilicon
    Abraham, Mariham Y.
    Wang, Yuzhong
    Xie, Yaoming
    Wei, Pingrong
    Schaefer, Henry F., III
    Schleyer, Paul V. R.
    Robinson, Gregory H.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (23) : 8874 - 8876
  • [3] Carbene Stabilization of Diarsenic: From Hypervalency to Allotropy
    Abraham, Mariham Y.
    Wang, Yuzhong
    Xie, Yaoming
    Wei, Pingrong
    Schaefer, Henry F., III
    Schleyer, P. von R.
    Robinson, Gregory H.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (02) : 432 - 435
  • [4] An isolable and monomeric phosphorus radical that is resonance-stabilized by the vanadium(IV/V) redox couple
    Agarwal, Paresh
    Piro, Nicholas A.
    Meyer, Karsten
    Mueller, Peter
    Cummins, Christopher C.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (17) : 3111 - 3114
  • [5] Efficient generation of stable adducts of Si(II) dihydride using a donor-acceptor approach
    Al-Rafia, S. M. Ibrahim
    Malcolm, Adam C.
    McDonald, Robert
    Ferguson, Michael J.
    Rivard, Eric
    [J]. CHEMICAL COMMUNICATIONS, 2012, 48 (09) : 1308 - 1310
  • [6] Stabilization of the Heavy Methylene Analogues, GeH2 and SnH2, within the Coordination Sphere of a Transition Metal
    Al-Rafia, S. M. Ibrahim
    Malcolm, Adam C.
    Liew, Sean K.
    Ferguson, Michael J.
    Rivard, Eric
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (04) : 777 - 779
  • [7] Theoretical studies of multiple bonds in gallium-gallium and germanium-germanium compounds
    Allen, TL
    Fink, WH
    Power, PP
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (03): : 407 - 412
  • [8] [Anonymous], 1952, GMELIN HANDBUCH DER, V17, P476
  • [9] [Anonymous], 1986, ZH STRUKT KHIM
  • [10] Carbene-pnictinidene adducts
    Arduengo, AJ
    Calabrese, JC
    Cowley, AH
    Dias, HVR
    Goerlich, JR
    Marshall, WJ
    Riegel, B
    [J]. INORGANIC CHEMISTRY, 1997, 36 (10) : 2151 - 2158
12345678910