A molecular gate based on a porphyrin and a silver lock

被引:38
作者
Guenet, Aurelie
Graf, Ernest
Kyritsakas, Nathalie
Allouche, Lionel
Hosseini, Mir Wais
机构
[1] CNRS, UMR 7140, Chim Coordinat Organ Lab, F-67000 Strasbourg, France
[2] Univ Strasbourg 1, CNRS, Federat Rech Chim,FR 2351, Serv Commun RMN, F-67000 Strasbourg, France
关键词
D O I
10.1039/b706527b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A Sn(IV) metallaporphyrin bearing a 4-pyridyl group on one meso position and a handle equipped also with a pyridyl unit functions in solution as a molecular gate in the presence of silver cation: the complexation-decomplexation of Ag(I) corresponds to the opening and closing motions of the gate.
引用
收藏
页码:2935 / 2937
页数:3
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