Enhanced energy storage performance in Pb0.97La0.02(ZrxSn0.90-xTi0.10)O3 antiferroelectric ceramics

被引：14
作者：
Qiao, Peixin [1 ]
Chen, Xuefeng [1 ]
Liu, Zhen [1 ]
Wang, Genshui [1 ,2 ,3 ]
Dong, Xianlin [1 ,2 ,3 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Inorgan Funct Mat & Devices, Shanghai 200050, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, 1295 Dingxi Rd, Shanghai 200050, Peoples R China
[3] Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Beijing 100049, Peoples R China
来源：
MATERIALS LETTERS | 2020年 / 260卷
关键词：
Antiferroelectric ceramics; PLZST; Energy storage performance; DENSITY; RATIO;
D O I：
10.1016/j.matlet.2019.126877
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Both high energy density and high energy efficiency are indispensable as considering antiferroelectric materials for pulse power capacitor applications. However, the electrical hysteresis will inevitably limit the energy efficiency reported in previous literatures. In this work, lead lanthanum zirconate stannate titanate (PLZST) antiferroelectrics with both high energy density and high energy efficiency was presented. It is found that PLZST antiferroelectric ceramics with high Sn content not only exhibit enhanced antiferroelectricity, but also demonstrate higher energy efficiency. As Sn content increases, grain size decreases and the electric hysteresis values reduces. The high energy density of 1.28 J/cm(3) and ultrahigh energy efficiency of 91% was obtained for PLZST30/60/10. The results will not only enrich our understanding of PLZST antiferroelectric materials but also offers new approach to developing high performance antiferroelectric for energy storage based applications. (C) 2019 Elsevier B.V. All rights reserved.
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页数：4
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