Enantioselective aziridination and amination using p-toluenesulfonyl azide in the presence of Ru(salen)(CO) complex

被引：88

作者：

Omura, K

Murakami, M

Uchida, T

Irie, R

Katsuki, T ^{[1
]}

机构：

[1] Kyushu Univ, Grad Sch, Fac Sci, Dept Chem,Higashi Ku, Fukuoka 8128581, Japan

[2] Japan Sci & Technol, CREST, Higashi Ku, Fukuoka 8128581, Japan

来源：

CHEMISTRY LETTERS | 2003年 / 32卷 / 04期

关键词：

D O I：

10.1246/cl.2003.354

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(R,R)-Ru(salen)(CO) complex (1) was found to catalyze enantioselective aziridination of conjugated terminal olefins and allylic C-H amination of conjugated olefins bearing geminal- and/or trans-substituent(s) in the presence of p-toluenesulfonyl azide.

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页码：354 / 355

页数：2

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