Experimental densities, speeds of sound, derived volumes and compressibilities of H2O-KCl-MgCl2-CaCl2 and H2O-KCl-MgCl2-CaCl2-NaCl systems at ionic strength 3 mol kg-1 and at 298.15 K
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Badarayani, R
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Natl Chem Lab, Div Phys Chem, Poona 411008, Maharashtra, IndiaNatl Chem Lab, Div Phys Chem, Poona 411008, Maharashtra, India
Badarayani, R
[1
]
Patil, KR
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Natl Chem Lab, Div Phys Chem, Poona 411008, Maharashtra, IndiaNatl Chem Lab, Div Phys Chem, Poona 411008, Maharashtra, India
Patil, KR
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]
Kumar, A
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Natl Chem Lab, Div Phys Chem, Poona 411008, Maharashtra, IndiaNatl Chem Lab, Div Phys Chem, Poona 411008, Maharashtra, India
Kumar, A
[1
]
机构:
[1] Natl Chem Lab, Div Phys Chem, Poona 411008, Maharashtra, India
The experimental densities and speeds of sound, of H2O-KCl-MgCl2-CaCl2 and H2O-KCl-MgCl2-CaCl2-NaCl systems are reported at ionic strength 3 mol kg(-1) and at 298.15 K. Mean apparent molar volumes and adiabatic compressibilities are derived from these densities and speeds of sound, which are analysed in terms of Young's rule of mixing. The properties calculated from Delta(mix)V and Delta(mix) K show good agreement with those obtained from the experiments. (C) 2000 Elsevier Science B.V. All rights reserved.