Experimental densities, speeds of sound, derived volumes and compressibilities of H2O-KCl-MgCl2-CaCl2 and H2O-KCl-MgCl2-CaCl2-NaCl systems at ionic strength 3 mol kg-1 and at 298.15 K

被引:4
作者
Badarayani, R [1 ]
Patil, KR [1 ]
Kumar, A [1 ]
机构
[1] Natl Chem Lab, Div Phys Chem, Poona 411008, Maharashtra, India
关键词
density; speed of sound; electrolyte mixture; volume; adiabatic compressibility; Young's rule;
D O I
10.1016/S0378-3812(00)00351-4
中图分类号
O414.1 [热力学];
学科分类号
摘要
The experimental densities and speeds of sound, of H2O-KCl-MgCl2-CaCl2 and H2O-KCl-MgCl2-CaCl2-NaCl systems are reported at ionic strength 3 mol kg(-1) and at 298.15 K. Mean apparent molar volumes and adiabatic compressibilities are derived from these densities and speeds of sound, which are analysed in terms of Young's rule of mixing. The properties calculated from Delta(mix)V and Delta(mix) K show good agreement with those obtained from the experiments. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:197 / 206
页数:10
相关论文
共 18 条
[1]   SPEED OF SOUND IN PURE WATER [J].
DELGROSS.VA ;
MADER, CW .
JOURNAL OF THE ACOUSTICAL SOCIETY OF AMERICA, 1972, 52 (05) :1442-&
[2]   ISENTROPIC COMPRESSIBILITIES OF AQUEOUS-SOLUTIONS OF SOME ALKALI-HALIDES AT 298.15 K [J].
GUCKER, FT ;
STUBLEY, D ;
HILL, DJ .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1975, 7 (09) :865-873
[3]  
KAMUR A, 1992, CHEM ENG SCI, V47, P4217
[4]   DENSITY, THERMAL EXPANSIVITY, AND COMPRESSIBILITY OF LIQUID WATER FROM 0 DEGREES TO 150 DEGREESC - CORRELATIONS AND TABLES FOR ATMOSPHERIC-PRESSURE AND SATURATION REVIEWED AND EXPRESSED ON 1968 TEMPERATURE SCALE [J].
KELL, GS .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1975, 20 (01) :97-105
[5]   PHYSICOCHEMICAL STUDY OF DEAD-SEA WATERS .2. DENSITY-MEASUREMENTS AND EQUATION OF STATE OF DEAD-SEA WATERS AT 1 ATM [J].
KRUMGALZ, BS ;
MILLERO, FJ .
MARINE CHEMISTRY, 1982, 11 (05) :477-492
[6]   THERMODYNAMICS OF CONCENTRATED ELECTROLYTE MIXTURES .2. DENSITIES AND COMPRESSIBILITIES OF AQUEOUS NACL-CACL2 AT 25-DEGREES-C [J].
KUMAR, A ;
ATKINSON, G ;
HOWELL, RD .
JOURNAL OF SOLUTION CHEMISTRY, 1982, 11 (12) :857-870
[8]   DENSITIES AND APPARENT MOLAL VOLUMES OF AQUEOUS KCL-CACL2 MIXTURES AT 298.15 K [J].
KUMAR, A .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1986, 31 (01) :21-23
[9]   PREDICTION OF DENSITIES OF CONCENTRATED BRINES BY PITZER THEORY [J].
KUMAR, A .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1986, 31 (01) :19-20