A comprehensive NMR methodology to assess the composition of biobased and biodegradable polymers in contact with food

被引：10

作者：

Gratia, Audrey ^{[1
,2
]}

Merlet, Denis ^{[3
]}

Ducruet, Violette ^{[2
]}

Lyathaud, Cedric ^{[1
]}

机构：

[1] Lab Natl Metrol & Essais LNE, Dept Chim & Physicochim Mat, F-78197 Trappes, France

[2] INRA, UMR1145, F-91300 Massy, France

[3] Univ Paris 11, Inst Chim Mol & Mat Orsay, Equipe RMN Milieu Oriente, UMR CNRS 8182, F-91405 Orsay, France

来源：

ANALYTICA CHIMICA ACTA | 2015年 / 853卷

关键词：

Nuclear magnetic resonance spectroscopy; Additives; Polylactide; Food contact material; Quantification; SYNTHETIC PHENOLIC ANTIOXIDANTS; PACKAGING MATERIALS; BARRIER PROPERTIES; SIZE-EXCLUSION; PET BOTTLES; DEGRADATION; H-1-NMR; IDENTIFICATION; POLYOLEFINS; TEMPERATURE;

D O I：

10.1016/j.aca.2014.09.046

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A nuclear magnetic resonance (NMR) methodology was assessed regarding the identification and quantification of additives in three types of polylactide (PLA) intended as food contact materials. Additives were identified using the LNE/NMR database which clusters NMR datasets on more than 130 substances authorized by European Regulation No. 10/2011. Of the 12 additives spiked in the three types of PLA pellets, 10 were rapidly identified by the database and correlated with spectral comparison. The levels of the 12 additives were estimated using quantitative NMR combined with graphical computation. A comparison with chromatographic methods tended to prove the sensitivity of NMR by demonstrating an analytical difference of less than 15%. Our results therefore demonstrated the efficiency of the proposed NMR methodology for rapid assessment of the composition of PLA. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：477 / 485

页数：9

共 39 条

[1]

Averous L., 2008, POLYLACTIC ACID SYNT

[2]

Ayed N, 2013, ARABIAN J CHEM

[3] Chemical compounds and toxicological assessments of drinking water stored in polyethylene terephthalate (PET) bottles: A source of controversy reviewed [J].

Bach, Cristina ;

Dauchy, Xavier ;

Chagnon, Marie-Christine ;

Etienne, Serge .

WATER RESEARCH, 2012, 46 (03) :571-583

[4] Identification of polymer additives by liquid chromatography-mass spectrometry [J].

Block, C. ;

Wynants, L. ;

Kelchtermans, M. ;

De Boer, R. ;

Compernolle, F. .

POLYMER DEGRADATION AND STABILITY, 2006, 91 (12) :3163-3173

[5]

Bogaert JC, 2000, MACROMOL SYMP, V153, P287, DOI 10.1002/1521-3900(200003)153:1<287::AID-MASY287>3.0.CO

[6]

2-E

[7] Comprehensive on-line HPLC-GC for screening potential migrants from polypropylene into food: The effect of pulsed light decontamination as an example [J].

Castillo, Roberto ;

Biedermann, Maurus ;

Riquet, Anne-Marie ;

Grob, Koni .

POLYMER DEGRADATION AND STABILITY, 2013, 98 (09) :1679-1687

[8] SAFETY ASSESSMENT OF POLYLACTIDE (PLA) FOR USE AS A FOOD-CONTACT POLYMER [J].

CONN, RE ;

KOLSTAD, JJ ;

BORZELLECA, JF ;

DIXLER, DS ;

FILER, LJ ;

LADU, BN ;

PARIZA, MW .

FOOD AND CHEMICAL TOXICOLOGY, 1995, 33 (04) :273-283

[9] Effect of abiotic factors on the degradation of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) in simulated and natural composting environments [J].

Eldsäter, C ;

Karlsson, S ;

Albertsson, AC .

POLYMER DEGRADATION AND STABILITY, 1999, 64 (02) :177-183

[10] Safety and quality of food contact materials. Part 1: Evaluation of analytical strategies to introduce migration testing into good manufacturing practice [J].

Feigenbaum, A ;

Scholler, D ;

Bouquant, J ;

Brigot, G ;

Ferrier, D ;

Franz, R ;

Lillemark, L ;

Riquet, AM ;

Petersen, JH ;

van Lierop, B ;

Yagoubi, N .

FOOD ADDITIVES AND CONTAMINANTS, 2002, 19 (02) :184-201

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