Bio-oil from residues of short rotation coppice of poplar using a microwave assisted pyrolysis

被引:31
作者
Bartoli, Mattia [1 ]
Rosi, Luca [1 ]
Giovannelli, Alessio [2 ]
Frediani, Piero [1 ]
Frediani, Marco [1 ]
机构
[1] Univ Florence, Dept Chem, Via Lastruccia 3-13, I-50019 Sesto Fiorentino, Italy
[2] CNR IVALSA, Via Madonna del Piano 10, I-50019 Sesto Fiorentino, Italy
关键词
Microwave; Pyrolysis; Biomass; Waste; Raw material; WATER-DEFICIT; BIOMASS; CELLULOSE; CARBON; FUEL; LEAF;
D O I
10.1016/j.jaap.2016.03.001
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Stump-roots and leaves from different residues of short rotation coppice (SRC) of poplar clones were transformed with microwave assisted pyrolysis to produce bio-oils. These products were obtained with high yield (up to 32.0%) and small water percentage (up to 17.5%), showed low density and viscosity and were fluid at room temperature. Bio-oils were characterized with several analytical techniques: H-1 NMR, lR-ATR, and an original and a quantitative GC-MS method. Acetic and formic acids, acetic anhydride, furanes and various phenols were identified and quantified; among bio-oils a sample with high acetic acid concentration (543.3 mg/mL) was obtained. These techniques let to make possible a detailed study on the bio-oils to define a correlation between their chemical and rheological properties with the clones employed and parameters of the process. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:224 / 232
页数:9
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