Incorporation of CO2-Derived Bicyclic Lactone into ConventionalVinyl Polymers

被引：18

作者：

Hill, Megan R. ^{[1
,2
]}

Tang, Shan ^{[1
,3
]}

Masada, Koichiro ^{[1
]}

Hirooka, Yuko ^{[1
]}

Nozaki, Kyoko ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem & Biotechnol, Grad Sch Engn, Tokyo 1138656, Japan

[2] MIT, Dept Chem, 77 Massachusetts Ave, Cambridge, MA 02139 USA

[3] Shanghai Jiao Tong Univ, Frontiers Sci Ctr Transformat Mol, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China

来源：

MACROMOLECULES | 2022年 / 55卷 / 08期

关键词：

CARBON-DIOXIDE; METHYL-METHACRYLATE; FUNCTIONALIZED POLYETHYLENES; THERMAL-PROPERTIES; COPOLYMERIZATION; ETHYLENE; CO2; POLYMERIZATION; 1,3-BUTADIENE; BUTADIENE;

D O I：

10.1021/acs.macromol.1c02503

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The ability to copolymerize monomers vastly increases the range of accessible material properties for a specificmonomer. We investigate the radical copolymerization of the lactone monomer (3-ethylidene-6-vinyltetrahydro-2H-pyran-2-one)(EVP) made from butadiene and carbon dioxide. The unique bicyclic structure provided by the EVP unit resulted in an elevation ofthe glass transition temperature across a range of commodity polymers and enabled the incorporation of functionality into EVP-based copolymers

引用

页码：3311 / 3316

页数：6

共 36 条

[1] A Review of the Properties and Applications of Poly (Methyl Methacrylate) (PMMA) [J].