Enhanced association for C70 over C60 with a metal complex with corannulene derivate ligands

被引：48

作者：

Alvarez, Celedonio M. ^{[1
]}

Garcia-Escudero, Luis A. ^{[1
]}

Garcia-Rodriguez, Raul ^{[1
]}

Martin-Alvarez, Jose M. ^{[1
]}

Miguel, Daniel ^{[1
]}

Rayon, Victor M. ^{[2
]}

机构：

[1] Univ Valladolid, Fac Ciencias, GIR MIOMeT IU CINQUIMA Quim Inorgan, E-47011 Valladolid, Spain

[2] Univ Valladolid, Fac Ciencias, E-47011 Valladolid, Spain

来源：

DALTON TRANSACTIONS | 2014年 / 43卷 / 42期

关键词：

CARBON NANOTUBES; COORDINATION; CORONENE;

D O I：

10.1039/c4dt02078b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The geometry imposed by the coordination sphere around the metal, together with the choice of the "arms" can be advantageously used to build corannulene-based molecular tweezers, which show great affinities for C-60 and C-70, as revealed by NMR titration experiments, mass spectroscopy, DFT calculations and the single crystal X-ray structural analysis of the compound C-60 subset of 1.

引用

页码：15693 / 15696

页数：4

共 21 条

[1]

[Anonymous], 2007, Core Concepts in Supramolecular Chemistry and Nanochemistry

[2]

Attwood J. L., 2004, ENCY SUPRAMOLECULAR

[3] N-Aryl Pyrrolo-tetrathiafulvalene Based Ligands: Synthesis and Metal Coordination [J].

Balandier, Jean-Yves ;

Chas, Marcos ;

Dron, Paul I. ;

Goeb, Sebastien ;

Canevet, David ;

Belyasmine, Ahmed ;

Allain, Magali ;

Salle, Marc .

JOURNAL OF ORGANIC CHEMISTRY, 2010, 75 (05) :1589-1599

[4] STRUCTURAL SPECIFICITY IN ASYMMETRIC CHARGE-TRANSFER COMPLEXATION OF HELICENES [J].

BROWN, JM ;

FIELD, IP ;

SIDEBOTTOM, PJ .

TETRAHEDRON LETTERS, 1981, 22 (48) :4867-4870

[5]

Canevet D., 2011, ANGEW CHEM INT EDIT, V50, P2

[6]

Canevet D, 2013, ORGANIC NANOMATERIALS: SYNTHESIS, CHARACTERIZATION, AND DEVICE APPLICATIONS, P147

[7] Self-assembly of cationic pyrene nanotubes [J].

Chen, Yulan ;

Zhu, Bo ;

Han, Yang ;

Bo, Zhishan .

JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (11) :4927-4931

[8]

Ermer O, 2001, HELV CHIM ACTA, V84, P1268, DOI 10.1002/1522-2675(20010613)84:6<1268::AID-HLCA1268>3.0.CO

[9]

2-Z

[10] Integrating single-wall carbon nanotubes into donor-acceptor nanohybrids [J].

Guldi, DM ;

Rahman, GMA ;

Jux, N ;

Tagmatarchis, N ;

Prato, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (41) :5526-5530

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