Hot isostatic pressing: thermal treatment trials of inactive and radioactive simulant UK intermediate level waste

Hot Isostatic Pressing (HIPing) is a batch process thermal treatment technology where wastes are heated and compressed within a sealed stainless steel canister; typically resulting in durable, high density ceramics or glasses with minimal loss of volatile elements, and accountability of active inventories. The University of Sheffield has a small-scale research HIP with capability to process simulant wasteforms containing radioactive materials, to help underpin larger-scale industrial applications of this technology. It was under this remit that a series of trials were undertaken, to produce small simulant radioactive wasteforms incorporating problematic UK waste streams such as Magnox sludges and clinoptilolite ion-exchange material. Each trial was successfully batched, sealed, and HIPed at 1250 degrees C, resulting in solidified products entirely contained within the steel HIP canisters. The ability to safely produce active wasteforms within the same facility validates the active furnace isolation chamber (AFIC) system. Overall the success of these trials demonstrate the ability of smaller research HIP facilities to build up the scientific and technical case for further implementation of HIP technology as a viable waste treatment option.