A classical silver carbonyl complex [{MeB[3-(Mes)pz]3}Ag(CO)] and the related silver ethylene adduct [{MeB[3-(Mes)pz]3}Ag(C2H4)]

被引：36

作者：

Dias, H. V. Rasika ^{[1
]}

Fianchini, Mauro ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Arlington, TX 76019 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 13期

关键词：

alkene ligands; carbonyl ligands; coordination modes; N ligands; silver;

D O I：

10.1002/anie.200604084

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Sting in the tale: A thermally stable silver(I) ethylene complex and the first classical silver(I) carbonyl adduct (see structure) have been isolated using the nonfluorinated, relatively electron-rich scorpionate ligand [MeB{3-(Mes)pz}3]- (Mes = 2,4,6-trimethylphenyl, pz = pyrazolate). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2188 / 2191

页数：4

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