Oxidation of benzyl alcohol in the copper-doped ZIF-8 metal-organic framework with encapsulated nitroxyl radical

被引：4
作者：
Efremov, A. A. [1 ,2 ]
Poryvaev, A. S. [1 ]
Polyukhov, D. M. [1 ]
Gromilov, S. A. [2 ,3 ]
Fedin, M., V [1 ,2 ]
机构：
[1] Russian Acad Sci, Int Tomog Ctr, Siberian Branch, 3a Ul Inst Skaya, Novosibirsk 630090, Russia
[2] Novosibirsk Natl Res State Univ, 1 Ul Pirogova, Novosibirsk 630090, Russia
[3] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Branch, 3 Prosp Akad Lavrentieva, Novosibirsk 630090, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2022年 / 71卷 / 07期
关键词：
nitroxyl radicals; metal-organic frameworks; catalysis; TEMPO; ZIF-8; alcohols; aldehydes; benzyl alcohol; benzaldehyde; CATALYZED AEROBIC OXIDATION; MECHANISM; EFFICIENT; ALDEHYDES; EPR;
D O I：
10.1007/s11172-022-3548-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel heterogeneous catalytic system based on the TEMPO nitroxyl radical encapsulated into the cavities of copper-doped ZIF-8 metal-organic framework was synthesized and characterized using ESR spectroscopy and powder X-ray diffraction. This system provided a highly selective (>99%) oxidation of benzyl alcohol to benzaldehyde.
引用
收藏
页码：1422 / 1428
页数：7
相关论文
共 50 条
  • [41] Copper-doped strontium metal-organic framework: Dual-function active material for supercapacitor and oxygen evolution reaction
    Al Mahmud, Abdullah
    Alshatteri, Azad H.
    Alhasan, Huda S.
    Al Zoubi, Wail
    Omer, Khalid M.
    Thalji, Mohammad R.
    ELECTROCHIMICA ACTA, 2024, 503
  • [42] Metal-organic framework-derived carbons: Preparation from ZIF-8 and application in the adsorptive removal of sulfamethoxazole from water
    Ahmed, Imteaz
    Bhadra, Biswa Nath
    Lee, Hye Jin
    Jhung, Sung Hwa
    CATALYSIS TODAY, 2018, 301 : 90 - 97
  • [43] Recombinant streptococcal protein G-modified metal-organic framework ZIF-8 for the highly selective purification of immunoglobulin G from human serum
    Ma, Yufei
    Xiang, Yuhan
    Li, Xin
    Zhang, Dandan
    Chen, Qing
    ANALYTICA CHIMICA ACTA, 2024, 1288
  • [44] Nonideality in the Adsorption of Ethanol/Ethyl Acetate/Water Mixtures On ZIF-8 Metal Organic Framework
    Virdis, Thomas
    Danilov, Valery
    Baron, Gino V.
    Denayer, Joeri F. M.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2018, 57 (20) : 7040 - 7047
  • [45] ZIF-8 Metal Organic Framework for the Conversion of Glucose to Fructose and 5-Hydroxymethyl Furfural
    Oozeerally, Ryan
    Ramkhelawan, Shivendra D. K.
    Burnett, David L.
    Tempelman, Christiaan H. L.
    Degirmenci, Volkan
    CATALYSTS, 2019, 9 (10)
  • [46] Catalytic synthesis of vitamin E acetate using metal organic framework material ZIF-8
    Li, Mingzhe
    Zhou, Yuyang
    Zhou, Hua
    Lu, Dingqiang
    JOURNAL OF COORDINATION CHEMISTRY, 2025, : 676 - 689
  • [47] Nanoscale zero-valent iron immobilized by ZIF-8 metal-organic frameworks for enhanced removal of hexavalent chromium
    Zhou, Long
    Yi, Yunqiang
    Fang, Zhanqiang
    CHEMOSPHERE, 2022, 306
  • [48] Poly(ethylene glycol) Stabilized Mesoporous Metal-Organic Framework Nanocrystals: Efficient and Durable Catalysts for the Oxidation of Benzyl Alcohol
    Xue, Zhimin
    Zhang, Jianling
    Peng, Li
    Han, Buxing
    Mu, Tiancheng
    Li, Jianshen
    Yang, Guanying
    CHEMPHYSCHEM, 2014, 15 (01) : 85 - 89
  • [49] Amine-functionalized metal-organic framework ZIF-8 toward colorimetric CO2 sensing in indoor air environment
    Davey, Adrian K.
    Gao, Xiang
    Xia, Yong
    Li, Zhou
    Dods, Matthew N.
    Delacruz, Steven
    Pan, Aifei
    Swamy, Sanket
    Gardner, David
    Carraro, Carlo
    Maboudian, Roya
    SENSORS AND ACTUATORS B-CHEMICAL, 2021, 344
  • [50] Zinc Imidazolate Metal-Organic Frameworks (ZIF-8) for Electrochemical Reduction of CO2 to CO
    Wang, Yulin
    Hou, Pengfei
    Wang, Zhuo
    Kang, Peng
    CHEMPHYSCHEM, 2017, 18 (22) : 3142 - 3147
12345