Oxidation of benzyl alcohol in the copper-doped ZIF-8 metal-organic framework with encapsulated nitroxyl radical

被引：4
作者：
Efremov, A. A. [1 ,2 ]
Poryvaev, A. S. [1 ]
Polyukhov, D. M. [1 ]
Gromilov, S. A. [2 ,3 ]
Fedin, M., V [1 ,2 ]
机构：
[1] Russian Acad Sci, Int Tomog Ctr, Siberian Branch, 3a Ul Inst Skaya, Novosibirsk 630090, Russia
[2] Novosibirsk Natl Res State Univ, 1 Ul Pirogova, Novosibirsk 630090, Russia
[3] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Branch, 3 Prosp Akad Lavrentieva, Novosibirsk 630090, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2022年 / 71卷 / 07期
关键词：
nitroxyl radicals; metal-organic frameworks; catalysis; TEMPO; ZIF-8; alcohols; aldehydes; benzyl alcohol; benzaldehyde; CATALYZED AEROBIC OXIDATION; MECHANISM; EFFICIENT; ALDEHYDES; EPR;
D O I：
10.1007/s11172-022-3548-5
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel heterogeneous catalytic system based on the TEMPO nitroxyl radical encapsulated into the cavities of copper-doped ZIF-8 metal-organic framework was synthesized and characterized using ESR spectroscopy and powder X-ray diffraction. This system provided a highly selective (>99%) oxidation of benzyl alcohol to benzaldehyde.
引用
收藏
页码：1422 / 1428
页数：7
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