Toward atomic resolution diffractive imaging of isolated molecules with X-ray free-electron lasers

被引：29

作者：

Stern, S. ^{[1
,2
]}

Holmegaard, L. ^{[1
,5
]}

Filsinger, F. ^{[6
,7
]}

Rouzee, A. ^{[8
,9
]}

Rudenko, A. ^{[7
,10
,11
]}

Johnsson, P. ^{[12
]}

Martin, A. V. ^{[1
]}

Barty, A. ^{[1
]}

Bostedt, C. ^{[13
]}

Bozek, J. ^{[13
]}

Coffee, R. ^{[13
]}

Epp, S. ^{[7
,10
]}

Erk, B. ^{[3
,7
,10
]}

Foucar, L. ^{[7
,14
]}

Hartmann, R. ^{[15
]}

Kimmel, N. ^{[16
]}

Kuehnel, K-U. ^{[10
]}

Maurer, J. ^{[5
]}

Messerschmidt, M. ^{[13
]}

Rudek, B. ^{[7
,10
]}

Starodub, D. ^{[17
]}

Thogersen, J. ^{[5
]}

Weidenspointner, G. ^{[16
,18
]}

White, T. A. ^{[1
]}

Stapelfeldt, H. ^{[5
,19
]}

Rolles, D. ^{[3
,14
]}

Chapman, H. N. ^{[1
,2
,4
]}

Kuepper, J. ^{[1
,2
,4
]}

机构：

[1] Deutsch Elektronen Synchrotron DESY, Ctr Free Electron Laser Sci CFEL, D-22607 Hamburg, Germany

[2] Univ Hamburg, Dept Phys, D-22761 Hamburg, Germany

[3] Deutsch Elektronen Synchrotron DESY, D-22607 Hamburg, Germany

[4] Univ Hamburg, Hamburg Ctr Ultrafast Imaging, D-22761 Hamburg, Germany

[5] Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark

[6] MPG, Fritz Haber Inst, D-14195 Berlin, Germany

[7] CFEL, Max Planck Adv Study Grp, D-22607 Hamburg, Germany

[8] FOM Inst AMOLF, NL-1098 XG Amsterdam, Netherlands

[9] Max Born Inst, D-12489 Berlin, Germany

[10] Max Planck Inst Nucl Phys, D-69117 Heidelberg, Germany

[11] Kansas State Univ, Dept Phys, JR Macdonald Lab, Manhattan, KS 66506 USA

[12] Lund Univ, Dept Phys, S-22100 Lund, Sweden

[13] SLAC Natl Accelerator Lab, Linac Coherent Light Source, Menlo Pk, CA 94025 USA

[14] Max Planck Inst Med Res, D-69120 Heidelberg, Germany

[15] PNSensor GmbH, D-81739 Munich, Germany

[16] Max Planck Semicond Lab, D-81739 Munich, Germany

[17] Arizona State Univ, Dept Phys, Tempe, AZ 85287 USA

[18] Max Planck Inst Extraterr Phys, D-85741 Garching, Germany

[19] Aarhus Univ, Interdisciplinary Nanosci Ctr INANO, DK-8000 Aarhus C, Denmark

来源：

FARADAY DISCUSSIONS | 2014年 / 171卷

基金：

瑞典研究理事会;

关键词：

PROTEIN NANOCRYSTALLOGRAPHY; ALIGNING MOLECULES; GAS-PHASE; FIELDS; PULSES; SCATTERING; ALIGNMENT; DYNAMICS; SAMPLES; FLIGHT;

D O I：

10.1039/c4fd00028e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We give a detailed account of the theoretical analysis and the experimental results of an X-ray-diffraction experiment on quantum-state selected and strongly laser-aligned gasphase ensembles of the prototypical large asymmetric rotor molecule 2,5-diiodobenzonitrile, performed at the Linac Coherent Light Source [Phys. Rev. Lett. 112, 083002 (2014)]. This experiment is the first step toward coherent diffractive imaging of structures and structural dynamics of isolated molecules at atomic resolution, i.e., picometers and femtoseconds, using X-ray free-electron lasers.

引用

页码：393 / 418

页数：26

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