Medium-range order and viscosity of molten Cu-23% Sn alloy

被引：32

作者：

Bian, XF ^{[1
]}

Sun, MH ^{[1
]}

Xue, XY ^{[1
]}

Qin, XB ^{[1
]}

机构：

[1] Shandong Univ, Minist Educ, Key Lab Liquid Struct & Hered mat, Jinan 250061, Peoples R China

来源：

MATERIALS LETTERS | 2003年 / 57卷 / 13-14期

基金：

中国国家自然科学基金;

关键词：

medium-range order; viscosity; alloy;

D O I：

10.1016/S0167-577X(02)01120-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The structures of molten Cu-23% Sn alloy at different temperatures have been determined by using a high-temperature Xray diffractometer. It has been found that there exist not only short-range order (SRO) structure but also medium-range order (MRO) structure in the molten alloy. The medium-range order structure in the alloy melt is a function of temperature. There exist obvious medium-range order structure at the range of temperatures from 900 to 1200 degreesC. The medium-range order structure disappears when the temperature reaches 1300 degreesC. The temperature dependence of the dynamic viscosity of the alloy melt has been measured using a torsional oscillation viscometer. It has been found that there is an abnormal change in the relationship between the temperature and the viscosity of the alloy melt. The abnormity change is consistent with the transformation from medium-range order to short-range order in the alloy melt. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：2001 / 2006

页数：6

共 19 条

[1] ON TEMPERATURE DEPENDENCE OF COOPERATIVE RELAXATION PROPERTIES IN GLASS-FORMING LIQUIDS [J].

ADAM, G ;

GIBBS, JH .

JOURNAL OF CHEMICAL PHYSICS, 1965, 43 (01) :139-&

[2] STRUCTURE OF LIQUID NA-SN ALLOYS [J].

ALBLAS, BP ;

VANDERLUGT, W ;

DIJKSTRA, J ;

GEERTSMA, W ;

VANDIJK, C .

JOURNAL OF PHYSICS F-METAL PHYSICS, 1983, 13 (12) :2465-2477

[3]

[Anonymous], METALLOFIZIKA

[4] Medium-range order clusters in metal melts [J].

Bian, XF ;

Pan, XM ;

Qin, XB ;

Jiang, MH .

SCIENCE IN CHINA SERIES E-TECHNOLOGICAL SCIENCES, 2002, 45 (02) :113-119

[5] Medium range order and microstructure of Al-1% Fe alloy [J].

Bian, XF ;

Qin, JY ;

Wang, WM ;

Qi, XG .

ALUMINIUM ALLOYS: THEIR PHYSICAL AND MECHANICAL PROPERTIES, PTS 1-3, 2000, 331-3 :343-348

[6] Structure factors of modified liquid Al-Si alloys [J].

Bian Xiufang ;

Wang Weimin ;

Yuan Shujuan ;

Qin Jingyu .

SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 2001, 2 (01) :19-23

[7] A GENERAL KINETIC THEORY OF LIQUIDS .3. DYNAMICAL PROPERTIES [J].

BORN, M ;

GREEN, HS .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1947, 190 (1023) :455-474

[8] Medium-range order around titanium in a silicate glass studied by neutron diffraction with isotropic substitution [J].

Cormier, L ;

Gaskell, PH ;

Calas, G ;

Soper, AK .

PHYSICAL REVIEW B, 1998, 58 (17) :11322-11330

[9] X-RAY MEASUREMENT OF ORDER IN SINGLE CRYSTALS OF (CU3AU) [J].

COWLEY, JM .

JOURNAL OF APPLIED PHYSICS, 1950, 21 (01) :24-29

[10] MEDIUM-RANGE STRUCTURAL ORDER IN COVALENT AMORPHOUS SOLIDS [J].

ELLIOTT, SR .

NATURE, 1991, 354 (6353) :445-452

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