Mesoporous TiO2 modified with carbon quantum dots as a high-performance visible light photocatalyst

被引:216
作者
Miao, Ran [1 ]
Luo, Zhu [2 ]
Zhong, Wei [2 ]
Chen, Sheng-Yu [1 ]
Jiang, Ting [3 ]
Dutta, Biswanath [1 ]
Nasr, Youmna [1 ]
Zhang, Yashan [1 ]
Suib, Steven L. [1 ,2 ]
机构
[1] Univ Connecticut, Dept Chem, U-3060, Storrs, CT 06269 USA
[2] Univ Connecticut, Inst Mat Sci, U-3136, Storrs, CT 06269 USA
[3] Univ Connecticut, Dept Chem & Biomol Engn, Storrs, CT 06269 USA
关键词
Photocatalysts; UCT mesoporous TiO2; Carbon quantum dot; Up-conversion; Visible light irradiation; INVERSE MICELLE SYNTHESIS; UP-CONVERSION; EFFICIENT; NANOPARTICLES; NANOCRYSTALS; CRYSTALLINE; COMPOSITES; NANODOTS; BLUE; NANOSTRUCTURES;
D O I
10.1016/j.apcatb.2016.01.070
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report a preparation method for visible light responsive Carbon Quantum Dots (CQDs) embedded in mesoporous TiO2 materials. The as-prepared mesoporous TiO2 (meso-Ti-450) material is a member of the recently designed University of Connecticut (UCT) mesoporous materials family. The UCT materials were synthesized based on sol-gel chemistry. The nanoparticles are randomly packed in inverse surfactant micelles and mesopores are formed by interconnected intraparticles. To achieve full usage of the visible region of sunlight (>400 nm), CQDs were introduced without destroying the mesopores. The photocatalytic performance of the CQDs/meso-Ti-450 was investigated by the degradation of methylene blue. Due to the up-conversion property and electron withdrawing property of CQDs, the photocatalytic activity of the composite material was largely enhanced under visible light irradiation. The highest photocatalytic activity was achieved by 5% CQDs/meso-Ti-450 in an hour. Compared to commercial P25, which is capable of removing 10% methylene blue (MB) under visible light conditions, the 5% CQDs/meso-Ti-450 can mostly remove MB (98%) under the same conditions. To date, the usage of mesoporous titanium oxide and carbon material composites for dye degradation under visible light has not been reported. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:26 / 38
页数:13
相关论文
共 72 条
[1]   Probing the role of thermally reduced graphene oxide in enhancing performance of TiO2 in photocatalytic phenol removal from aqueous environments [J].
Adamu, Haruna ;
Dubey, Prashant ;
Anderson, James A. .
CHEMICAL ENGINEERING JOURNAL, 2016, 284 :380-388
[2]   Adsorption of Dyes on Hierarchical Mesoporous TiO2 Fibers and Its Enhanced Photocatalytic Properties [J].
Bao, Nan ;
Li, Yuan ;
Wei, Zhentao ;
Yin, Guangbin ;
Niu, Junjian .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (13) :5708-5719
[3]   Synthesis of colloidal upconverting NaYF4: Er3+/Yb3+ and Tm3+/Yb3+ monodisperse nanocrystals [J].
Boyer, John-Christopher ;
Cuccia, Louis A. ;
Capobianco, John A. .
NANO LETTERS, 2007, 7 (03) :847-852
[4]   Synthesis of colloidal upconverting NaYF4 nanocrystals doped with Er3+, Yb3+ and Tm3+, Yb3+ via thermal decomposition of lanthanide trifluoroacetate precursors [J].
Boyer, John-Christopher ;
Vetrone, Fiorenzo ;
Cuccia, Louis A. ;
Capobianco, John A. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (23) :7444-7445
[5]   Carbon dots for multiphoton bioimaging [J].
Cao, Li ;
Wang, Xin ;
Meziani, Mohammed J. ;
Lu, Fushen ;
Wang, Haifang ;
Luo, Pengju G. ;
Lin, Yi ;
Harruff, Barbara A. ;
Veca, L. Monica ;
Murray, Davoy ;
Xie, Su-Yuan ;
Sun, Ya-Ping .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (37) :11318-+
[6]   The electronic origin of the visible-light absorption properties of C-, N- and S-doped TiO2 nanomaterials [J].
Chen, Xiaobo ;
Burda, Clemens .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (15) :5018-+
[7]   Versatile synthesis strategy for carboxylic acid-functionalized upconverting nanophosphors as biological labels [J].
Chen, Zhigang ;
Chen, Huili ;
Hu, He ;
Yu, Mengxiao ;
Li, Fuyou ;
Zhang, Qiang ;
Zhou, Zhiguo ;
Yi, Tao ;
Huang, Chunhui .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (10) :3023-3029
[8]   Improved Catalytic Capability of Mesoporous TiO2 Microspheres and Photodecomposition of Toluene [J].
Feng, Yinchang ;
Li, Lei ;
Ge, Ming ;
Guo, Changsheng ;
Wang, Junfeng ;
Liu, Lu .
ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (11) :3134-3140
[9]   Synergetic Effects of Ultraviolet and Microwave Radiation for Enhanced Activity of TiO2 Nanoparticles in Degrading Organic Dyes Using a Continuous-Flow Reactor [J].
Genuino, Homer C. ;
Hamal, Dambar B. ;
Fu, You-Jun ;
Suib, Steven L. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (26) :14040-14051
[10]   Microwave-Assisted Polyol Synthesis of Gadolinium-Doped Green Luminescent Carbon Dots as a Bimodal Nanoprobe [J].
Gong, Ningqiang ;
Wang, Hao ;
Li, Shuai ;
Deng, Yunlong ;
Chen, Xiao'ai ;
Ye, Ling ;
Gu, Wei .
LANGMUIR, 2014, 30 (36) :10933-10939